专利摘要:
abstract “herbicidal composition comprising uracil compound as active ingredient”. The present invention relates to a herbicidal composition comprising, as active ingredients, a herbicidally active compound and a uracil compound or an agrochemically acceptable salt thereof. the herbicidal composition has excellent effects not only in the selective control of monocots and dicots weeds in useful plant species, but also in the control of monocots and dicots weeds in semi-selective and non-selective areas.
公开号:BR112014025474B1
申请号:R112014025474-5
申请日:2013-04-12
公开日:2019-10-08
发明作者:Kyoung Sung Kim;In Young Choi;Mi Sook Hong;Tae Joon Kim;Jun Hyuk Choi;Gi Jun Moon
申请人:Dongbu Farm Hannong Co., Ltd.;
IPC主号:
专利说明:

“HERBICIDE COMPOSITION UNDERSTANDING URACIL COMPOUND AS AN ACTIVE INGREDIENT”
FIELD OF TECHNIQUE [001] The present invention relates to a herbicidal composition comprising uracil compound as an active ingredient.
BACKGROUND OF THE TECHNIQUE [002] Uracil compounds are known as useful herbicidally active compounds. German Patent Publication no. 714,602, International Patent Publication No. WO 96/07323 and Publication Open to Japanese Patent Inspection No. Hei 11-189506 describe herbicidal compositions comprising an uracil compound as an active ingredient. However, Korean Patent No. 1,103,840 registered in the applicant's name describes a new uracil compound and a herbicidal composition comprising it as an active ingredient.
[003] However, there is a continuing demand for a broad spectrum herbicidal composition that exhibits a remarkable synergistic effect greater than two or more herbicidally active compounds and has selective, semi-selective and / or non-selective activity against monocotyledonous and / or dicotyledonous weeds on various plants.
MODE FOR THE INVENTION [004] It is therefore an object of the present invention to provide a herbicidal composition with remarkable synergistic effect, which comprises a herbicidally active compound selected from uracil compounds and another herbicidally active compound.
[005] Another objective of the present invention is to provide a broad spectrum herbicidal composition with selective, semi-selective and / or non-selective activity against monocotyledonous and / or dicotyledonous weeds in various plants, wherein the herbicidal composition comprises a herbicidally active compound selected from from uracil compounds and another herbicidally active compound.
Petition 870170050929, of 07/20/2017, p. 8/70
2/58 [006] To achieve the above objectives, the present invention provides a herbicidal composition comprising, as active ingredients, a herbicidally active compound and a uracil compound represented by formula 1 or an agrochemically acceptable salt thereof:
Formula 1
i ch 3
In Formula 1, [007] R 1 and R 2 are the same or different and represent a hydrogen atom or a C1-C6 alkyl group; R 3 represents a hydrogen atom, a hydroxyl group, a C1-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group, a C1-C8 alkoxy group, a C1-C6 haloalkyl group, a C2 group -C6 haloalkenyl, a C1-C6 alkoxy C1-C6 alkyl group, or a C6-C10 aryl C1-C6 alkoxy group; R4 represents a hydrogen atom, a C1-C6 alkyl group, a C1-C6 haloalkyl group or a C1-C6 alkoxycarbonyl C1-C6 alkyl group; R 5 represents a hydrogen atom, a C1-C6 alkyl group, a C1-C6 alkoxy group, a C2-C6 haloalkyl group, a C2-C6 alkenyl group, a C2-C6 haloalkenyl group, a C2-C6 alkynyl group, a C1-C6 alkoxycarbonyl group, a C1-C6 alkyl group, a C6-C10 aryl C1-C6 alkyl group or a C6-C10 aryl C1-C6 alkoxy group; X represents O, S, SO, SO2, NH or N (C1-C6 alkyl); Y represents a C1-C6 alkylene group or a C1-C6 haloalkylene group; W represents O, S, NH or N (C1-C6 alkyl); and Z represents a halogen atom, a cyan group, CONH2 or CSNH2.
[008] In one embodiment of the present invention, the uracil compound is 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo methyl acid ester) -4-trifluoromethyl-1
Petition 870170050929, of 07/20/2017, p. 9/70
3/58 (2H) -pyrimidinyl) -4-fluorophenoxy] -1-oxopropyl} amino] propionic, or methyl acid ester
3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -4-fluorophenylthio] - 1-oxopropyl} amino] propionic.
[009] In one embodiment of the present invention, the herbicidally active compound is one or more selected from amide derivatives, heterocyclic aryl derivatives, aryloxyphenoxy propionate derivatives, carboxylic acid derivatives, benzothiadiazole derivatives, chloroacetamide derivatives, derivatives cyclohexanedione derivatives, diphenyl ether derivatives, urea derivatives, imidazolidinone derivatives, isoxazole derivatives, anilide nicotine derivatives, nitrile derivatives, organic phosphorus compounds, oxyacetamide derivatives, phenoxycarboxylic acid derivatives, pyrazole derivatives pyridazinone derivatives, pyridine derivatives, pyrimidinyl (thio) benzoate derivatives, sulfonylurea derivatives, tetrazolinone derivatives, thiazine derivatives, triazinone derivatives, triazolinone derivatives, triazolopyrimidine derivatives, tricacetone derivatives and uracil derivatives . In one embodiment of the present invention, the herbicidally active compound is one or more selected from 2-chloro-N- (ethoxymethyl) -N- (2-ethyl-6-methyl-phenyl) -acetamide (acetochlor), sodium acid salt 5- (2-chloro-4-triflu oromethyl-phenoxy) -2-nitro-benzoic (acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxy-benzenamine (aclonifene), 2-chloro-N- ( methoxymethyl) -N- (2,6-diethyl-phenyl) -acetamide (alachlor), N-ethyl-N'-iso-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (ametrine ), 4-amino-N (1,1-dimethyl-ethyl) -4,5-dihydro-3- (1-methyl-ethyl) -5-oxo-1H-1,2,4-triazole-1 -carboxamide (amicarbazone), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonyl-sulfamoyl) -urea (amidosulfurone), 1H-1,2,4- triazole-3-amine (amitrol), 6-chloro-4-ethylamino -2-isopropylamino-1,3,5-triazine (atrazine), 2- [2,4-dichloro-5- (2-propynyloxy) -phenyl ] -5,6,7,8-tetrahydro-1,2,4-triazole- [4,3-a] -pyridin-3 (2H) -one (azafenidin),
N- (4,6-dimethoxy-pyrimidin-2-yl) -N'-1- [methyl-4- (2-methyl-2H-tetrazol-5-yl) -1H-pyrazol-5-ylsulfonyl] - urea (azimsulfurone), N-benzyl-2- (4-fluoro-3-trifluoromethyl-phenoxy) -butanamide
Petition 870170050929, of 07/20/2017, p. 10/70
4/58 (beflubutamide), 4-chloro-2-oxo-3 (2H) -benzothiazolacetic acid (benazoline), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-benzenamine (benfluralin), N - (4,6-dimethoxy-pyrimidin-2-yl) -N- (2-methoxycarbonyl-phenylmethylsulfonyl) -urea (bensulfurone), methyl 2- [2- [4- (3,6-dihydro-3- methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) phenoxy] methyl] -5-ethyl-phenoxy-propanoate (benzfendizone), 3- (2-chloro-4-methylsulfonyl-benzyl) -4-phenylthio -bicyclo- [3.2.1] -oct-3-en-2-one (benzobicyclon), ethyl N-benzoyl-N- (3,4-dichloro-phenyl) -DL-alaninate (benzoylprop-ethyl), 3- i-propyl-1H-2,1,3-benzothiadiazin-4 (3H) -one (bentazone), methyl 5- (2,4-dichloro-phenoxy) -2-nitro-benzoate (biphenox), sodium acid salt 2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl-oxy) -benzoic (bispyribaque-sodium), 5-bromo-6-methyl-3- (1-methyl-propyl) -2,4 (1H, 3H) pyrimidinedione (bromacila), 2-bromo -3,3-dimethyl-N- (1-methyl-1-phenyl-ethyl) -butanamide (bromobutide), O- (2,4-dinitro-phenyl )
3,5-dibromo-4-hydroxy-benzaldehyde-oxime (bromophenoxime), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynyl), N-butoxymethyl-2-chloro-N- (2,6-diethyl-phenyl ) -acetamide (butachlor), [1,1-dimethyl-2-oxo-2- (2-propenyloxy)] - ethyl 2-chloro-5- (3,6-dihydro-3-methyl -2,6 -dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -benzoate (butafenacyl-ally),
2- (1-ethoxy-propyl) -3-hydroxy-5- [2,4,6-trimethyl-3- (1-oxo-butyl) -phenyl] -2-cyclohexen-1-o (butroxidim ), S-ethyl bis- (2-methyl-propyl) -thiocarbamate (butylate), N, N-diethyl-3- (2,4,6-trimethyl-phenylsulfonyl) -1H-1,2,4-triazole- 1-carboxamide (cafenstrol),
2- 1 - [(3-chloro-2-propenyl) -oxy-imino-propyl] -3-hydroxy-5- (tetrahydro-2H-pyran-4-yl) -2-cyclohexen-1- one (caloxidim, tepraloxidim), 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) -phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro -3H-1,2,4-triazole-3-one (carfentrazone-ethyl), 2,4-dichloro-1- (3-methoxy-4-nitro-phenoxy) -benzene (clomethoxyphen), acid
3- amino-2,5-dichloro-benzoic (chlorambene), N- (4-chloro-6-methoxy-pyrimdin-
2-yl) -N- (2-ethoxycarbonyl-phenylsulfonyl) -urea (chlorimuron-ethyl), 1,3,5-trichloro-2- (4-nitro-phenoxy) -benzene (clomitrophen), N- (4- methoxy-6-methyl-1,3,5-triazin-2-yl) -N- (2-chloro-phenylsulfonyl) -urea (chlorosulfurone), N- (3-chloro-4-methyl-phenyl) -N, N- dimethyl-urea (chlortolurone), ethyl 2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexahydro
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5/58
-1,3-dioxo-2H-isoindol-2-yl) -phenyl] -2-propanoate (cinidon-ethyl), N- (4,6-dimethoxy -1,3,5-triazin-2-yl) - N '- (2- (2-methoxy-ethoxy) -phenylsulfonyl) -urea (kinesulfurone),
2- [1- [2- (4-chloro-phenoxy) -propoxyamino] butyl] -5- (tetrahydro-2H-thiopyran-3-yl) -1,3-cyclohexanedione (clefoxidim), ( E, E) - (+) - 2- [1 - [[((3-chloro-2-propenyl) -oxy] -imino] -propyl] -3-hydroxy-2-cyclohexen-1-one (clethodim ), prop-2-ynyl (R) -2- [4- (5-chloro-3-fluoro-pyridin-2-yl-oxy) -phenoxy] -propanoate (clodinafop-propargyl), acid
3.6- dichloro-pyridine-2-carboxylic (clopyralide), methyl 3-chloro-2 - [(5-ethoxy-7
-fluoro [1,2,4] triazole [1,5-c] pyrimidin-2-yl-sulfonyl) -amino] -benzoate (chloransulam-methyl), 2-chloro-4-ethylamino-6- (1-cyano -1-methyl-ethylamino) -1,3,5-triazine (cyanazine), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (2-cyclopropylcarbonyl-phenylsulfonyl) -urea (cyclosulfamurone) , 2- (1-ethoxyiminobutyl) -3-hydroxy-5- (tetrahydro-2H-thiopyran-3-yl) -2-cyclohexen-1-one (cycloxydim), butyl (R) -2- [4- (4-cyano-2-fluoro-phenoxy) -phenoxy] -propanoate (cyhalophope-butyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), acid
3.6- dichloro-2-methoxy-benzoic (dicamba), (R) -2- (2,4-dichloro-phenoxy) -propanoic acid (dichlorprop-P), methyl-2- [4- (2,4-dichloro -phenoxy) -phenoxy] -propanoate (diclofop-methyl), N- (2,6-dichloro-phenyl) -5-ethoxy-7-fluoro- [1,2,4] -triazole- [1,5-c ] -pyrimidine-2-sulfonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methyl sulfate (difenzoquat), N- (2,4-difluoro-phenyl) -2- (3-trifluoromethyl- phenoxy) -pyridine-3-carboxamide (diflufenicano), 2- [1- (3,5-difluoro-phenyl) -amino-carbonyl-hydrazono-ethyl] -pyridine-3-carboxylic acid (diflufenzopyr), S- (1 -methyl-1-phenyl-ethyl) 1-piperidine-carbothioate (dimepiperate), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (2-methoxy-ethyl) -acetamide (dimetachlor), ( S) 2-chloro-N- (2,4-dimethyl-3-thienyl) -N- (2-methoxy-1-methyl-ethyl) -acetamide (S) (dimethenamide), 2-amino-4- (1 -fluoro-1-methyl-ethyl) -6- (1-methyl-2- (3,5-dimethyl-phenoxy) -ethylamino) -1,3,5-triazine (dimexiflam), N3, N3-diethyl- 2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (dinitramine), 6,7-dihydro-dipyride [1,2-a: 2,1- c] pyrazinadio (diquat), S, S-dimethyl 2-difluoromethyl-4-i-butyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopir),
N '- (3,4-dichloro-phenyl) -N, N-dimethyl-urea (diuron), 2-2- (3-chloro-phenyl) -oxyranylmethyl-2-ethylPetition 870170050929, of 20/07/2017, p. 12/70
6/58
1H-indene-1,3 (2H) -dione (epropodane), S-ethyl dipropylthiocarbamate (EPTC), S- (phenylmethyl) N-ethyl-N- (1,2-dimethylpropyl) -tiocarbamate (esprocarb),
N-ethyl-N- (2-methyl-2-propenyl) -2,6-dinitro-4-trifluoromethyl-benzenamine (etalfluralin), 2-ethoxy-1-methyl-2-oxoethyl (S) -2-chloro- 5- (2-chloro-4-trifluoromethyl-phenoxy) -benzoate (ethoxyphen), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (2-ethoxy-phenoxysulfonyl) -urea (ethoxysulfuron) , ethyl (R) -2- [4- (6-chloro-benzoxazol-2-yl-oxy) -phenoxy] -propanoate (phenoxaprop- (P) -ethyl),
4- (2-chloro-phenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1 H-tetrazol-1-carboxamide (fen-trazamide), N-benzoyl-N isopropyl - (3-chloro-4-fluoro-phenyl) -DL-alaninate (flamprop-isopropyl), isopropyl N-benzoyl-N- (3-chloro-4-fluoro-phenyl) -L-alaninate (flamprop-isopropyl-L ), methyl N-benzoyl-N- (3-chloro-4-fluoro-phenoxy) -DL-alaninate (flamprop-methyl), N- (2,6-difluoro-phenyl) -8-fluoro-5-methoxy [1,2,4] -triazole- [1,5-c]
-pyrimidine-2-sulfonamide (florassulam), butyl (R) -2- [4- (5-trifluoromethi
1- pyridin-2-yl-oxy) -phenoxy] -propanoate (fluazifop, -butyl, P-butyl), i-propyl
5- (4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-benzoate (fluazo-late), 4,5-dihydro- 3-methoxy-4-methyl-5-oxo-N - [(2-trifluoromethoxy-phenyl) -sulfonyl] -1 H-1,2,4-triazole-1-carboxamide (flucarbazone-sodium), N- (4 -fluoro-phenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (flufenacet),
N- (2,6-difluoro-phenyl) -5-methyl-1,2,4-triazole [1,5-a] -pyrimidine-2-sulfonamide (flumetsulam), pentyl [2-chloro-4-fluoro- 5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) -phenoxy] -acetate (flumiclorac-pentyl), 2- [7-fluoro -3,4-dihydro-3-oxo-4- (2-propynyl) 2H-1,4-benzoxazin-6-yl] -4,5,6,7-tetrahydro-1 H-isoindole- 1,3-dione (flumioxazin),
2- [4-chloro-2-fluoro-5- (1-methyl-2-propynyl) -oxy] -phenyl-4,5,6,7-tetrahydro-1 H-isoindol-1,3 (2 H) -dione (flumipropyn), 3-chloro-4-chloromethyl-1- (3-trifluoromethyl-phenyl) -2-pyrrolidinone (fluorochloridone), ethoxycarbonylmethyl 5- (2-chloro-4-trifluoromethyl-phenoxy) -2- nitro-benzoate (fluoroglycophene-ethyl), 1- (4-chloro-3- (2,2,3,3,3-pentafluoro-propoxymethyl) -phenyl) -5-phenyl1 H-1,2,4-triazole- 3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidyl) -benzoate ( flupropacil), sodium salt
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7/58 of N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl) -urea (flupirsulfuron-methyl-sodium), 9-hydroxy-9H-fluorene-9-carboxylic acid (flurenol), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy) -acetic acid (2-butoxy-1-methyl -ethyl ester, 1-methylheptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4- (3-trifluoromethyl-phenyl) -3 (2H) -furanone (flurtamone), methyl [(2-chloro-4-fluoro-5- (tetrahydro-3-oxo-1H, 3H- [1,3,4] -thiadiazole- [3,4-a] -pyridazin-1-ylid) -amino) -phenyl-thioacetate (fluthiacet-methyl), 5- (2-chloro-4-trifluoromethyl-phenoxy) -N-methylsulfonyl-2-nitro-benzamide (fomesafen), 2 - [[[[(4.6 -dimethoxy-2-pyrimidinyl) -amino] -carbonyl] -amino] -sulfonyl] -4-formylamino-N, N-dimethyl-benzamide (foramsulfuron), 2-amino-4- (hydroxymethylphosphinyl) ammonium salt - butanoic (glufosinate-ammonium), N-phosphonomethyl-glycine (isopropylammonium salt) (glyphosate, isopropylammonium), (R) -2- [4- (3-chloro-5-trifluorome tyl-pyridin-2-yl-oxy) -phenoxy] -propanoic (methyl ester,
2- ethoxy-ethyl ester, butyl ester) (haloxyphope, -methyl, P-methyl, -ethoxyethyl, -butyl),
3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4 (1H, 3H) -dione (hexazinone), methyl 2- (4,5-dihydro-4- methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate (imazametabenzo-methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl- 5-oxo1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic (imazametapyr), acid
2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- ( 4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol -2-yl) -quinoline-3-carboxylic acid (imazaquin), 2- (4,5-dihydro- 4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic (imazetapyr), N- (4,6-dimethoxy-pyrimidin-2-yl ) -N '- (2-chloro-imidazo- [1,2-a] -pyridin-3-yl-sulfonyl) -urea (imazosulfuron), N- (4-methoxy-6-methyl-1-sodium salt, 3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonyl-phenylsulfonyl) -urea (iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile (ioxynyl ), N, N-dimethyl-N '- (4-isopropyl-phenyl) -urea (isoproturone), N- (3- (1-ethyl-1-methyl-propyl) -isoxazol-5-yl) -2, 6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonyl-phenyl) - (5-cyclopropyl-isoxazol-4-yl) -methanone (isoxaclortol), (5-cyclopropyl-isoxaPetition 870170050929, from 20/07 / 2017, page 14/70
8/58 zol-4-yl) - (2-methylsulfonyl-4-trifluoromethyl-phenyl) -methanone (isoxaflutol),
2- [2- [4 - [(3,5-dichloro-2-pyridinyl) -oxy] -phenoxy] -1-oxo-propyl] -isoxazolidine (isoxapyrifop), (2-ethoxy-1-methyl-2- oxo-ethyl) -5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoate (lactofen), N- (3,4-dichloro-phenyl) -N-methoxy-N-methyl-urea ( linurone), (4-chloro-2-methyl-phenoxy) -acetic acid (MCPA), (±) -2- (4-chloro-2-methyl-phenoxy) -propionic acid (mecoprop),
2- (2-benzothiazolyloxy) -N-methyl-N-phenyl-acetamide (mefenacet), methyl [[[[2- (4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4- [[(methylsulfonyl) amino] methyl] -benzoate (mesosulfuron), 2- (4-methylsulfonyl-2-nitro-benzoyl) -1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6- phenyl-1,2,4-triazin-5 (4H) -one (metamitrone), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (1H-pyrazol-1-yl-methyl) - acetamide (metazachlor), N '- (4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy) -phenyl) -N- methoxy-Nmethyl-urea (metobenzurone), N '- (4-bromophenyl) -N-methoxy-N-methyl urea (metobromuron), (S) -2-chloro-N- (2-ethyl-6-methyl-phenyl ) -N- (2-methoxy-1-methyl-ethyl) -acetamide (metolachlor, S-metolachlor), N- (2,6-dichloro-3-methyl-phenyl) -5,7-dimethoxy-1 , 2,4-triazole [1,5-a] -pyrimidine-2-sulfonamide (metosulam), N '- (3-chloro-4-methoxy-phenyl) -N, N-di-ethyl-urea (methoxyurone) , 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4-methoxy-6-methyl-1,3,5- triazin-2-yl) -N '- (2-methoxycarbon il-phenylsulfonyl) -urea (metsulfuron-methyl), S-ethyl-hexahydro-1 H-azepine-1-carbothioate (molinate),
2- (2-naphthyloxy) -N-phenyl-propanamide (naproanilide), N-butyl-N '- (3,4-dichloro-phenyl)
-N-methyl-urea (neburone), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl) -urea (nicosulfuron), 4- chloro-5-methylamino-2- (3-trifluoromethyl-phenyl) -3 (2H) -pyridazinone (norflurazon), S- (2-chloro-benzyl) -N, N-diethyl-thiocarbamate (orbencarbon), 4-dipropylamino -3,5-dinitro-benzenesulfonamide (oryzaline),
3- [2,4-dichloro-5- (2-propynyloxy) -phenyl-5] - (t-butyl) -1,3,4-oxadiazole-2 (3H) -one (oxadiargyl),
3-2,4-dichloro-5- (1-methyl-ethoxy) -phenyl-5- (t-butyl) -1,3,4-oxadiazole-2 (3H) -one (oxadiazone), N- (4 , 6-dimethyl-pyrimidin-2-yl) -N '- (2-oxetan-3-yl-oxycarbonyl-phenylsulfonyl) -urea (oxassul
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9/58 furon), 3- [1 - (3,5-dichloro-phenyl) -1 -i-propyl] -2,3-dihydro-6-methyl-5-phenyl-4H-1,3- oxazin-4one (oxaziclomefone), 2-chloro-1- (3-ethoxy-4-nitro-phenoxy) -4-trifluoromethylbenzene (oxyfluorfen), 1,1'-dimethyl-4,4'-bipyridinium (paraquat), 1 -amino-N- (1-ethyl-propyl) -3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), 4- (t-butyl) -N- (1-ethyl-propyl) -2, 6-dinitro-benzenamine (pendralin), 4-amino-3,5,6-trichloro-pyridine-2-carboxylic acid (picloram), N- (4-fluoro-phenyl) -6- (3-trifluoromethyl-phenoxy) -pyridine-2-carboxamide (picolinafen), 2-chloro-N- (2,6-diethyl-phenyl) -N- (2-propoxy-ethyl) -acetamide (pretylachlor), N- (4,6-bis- difluoromethoxy-pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) -urea (primisulfuron-methyl), 1-chloro-N-2-chloro-4-fluoro-5 - [(6S, 7aR) - 6-fluorotetrahydro-
1.3- dioxo-1 H-pyrrole [1,2-c] imidazole-2 (3H) -yl-phenyl-methanesulfonamide (profluazole),
2-chloro-N-isopropyl-N-phenyl-acetamide (propachlor), N- (3,4-dichlorophenyl) -propanamide (propanyl), (R) - [2 - [[((1-methylethylidene) -amino] - oxy] -ethyl] -2- [4- (6-chloro-2-quinoxalinyloxy) -phenoxy] -propanoate (propaquiza-fope), 2-chloro-N- (2-ethyl-6-methyl
-phenyl) -N - [(1-methyl-ethoxy) -methyl] -acetamide (propisochlor), methyl salt [[[2- (4,5-dihydro-4-methyl-5-oxo-3- propoxy-1 H-1,2,4-triazol-1-yl) -carbonyl] -amino] -sulfoni
l] -Sodium benzoate (propoxycarbazone-sodium), S-phenylmethyl
N, N-dipropyl-thiocarbamate (prosulfocarb), N- (4-methoxy-6-methyl
-1,3,5-triazin-2-yl) -N '- (2- (3,3,3-trifluoro-propyl) -phenylsulfonyl) -urea (prosulfuron), ethyl [2-chloro-5- (4 -chloro-5-difluoromethoxy-1-methyl-1 H-pyrazol-3-yl) -4-fluoro-phenoxy] -acetate (piraflufen-ethyl), 1 - (3-chloro-4,5,6,7- tetrahydro-pyrazol [1,5-a] pyridin-2-yl) -5- (methyl-2propynylamino) -1 H-pyrazol-4-carbonitrile (pyrazogyl), 4- (2,4-dichloro-benzoyl) -
1.3-dimethyl-5- (4-methyl-phenylsulfonyloxy) -pyrazole (pyrazolate), 4- (2,4-dichloro-benzoyl) -1,3-di-methyl-5- (phenylcarbonylmethoxy) -pyrazole (pyrazoxifen), N '- (4,6-dimethoxy-pyrimidin-2-yl) -N- (4ethoxycarbonyl-1methyl-pyrazol-5-yl-sulfonyl) -urea (pyrazosulfuron-ethyl),
O- [2,6-bis- (4,6-dimethoxy-pyrimidin-2-yl-oxy) -benzoyl] diphenylmethanone-oxime (pyribenzoxy
m), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O- (6-chloro-3-phenyl-pyridazin-4-yl) S-octyl thiocarbonate (pyridate), 6-chloro-3-phenyl -pyridazin-4-ol (pyridatol),
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7 - [(4,6-dimethoxy-2-pyrimidinyl) -thio] -3-methyl-1 (3H) -iso-benzofuranone (Piriftalid), methyl 2- (4,6-dimethoxy-pyrimidin-2-yl- oxy) -benzoate (pyriminobaque-methyl), 2-chloro-6- (4,6-dimethoxy-pyrimidin-2-ylthio) -benzoic acid (piritiobaque-sodium) acid, 3,7-dichloro-quinoline- 8-carboxylic acid (quincloraque), 7-chloro-3-methyl-quinoline-8carboxylic acid (quinmeraque), 2- [4- (6-chloro-2-quinoxalinyloxy) -phenoxy] -propanoic acid (ethyl-ester, tetra- hydro-2-furanyl-methyl ester) (quizalofope, -ethyl, P-ethyl, P-tefuryl), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-ethylsulfonyl-pyridin- 2-yl-sulfonyl) -urea (rimsulfurone), 2- (1-ethoxyiminobutyl) -5- (2-ethylthiopropyl) -3-hydroxy-2-cyclohexen-1-one (setoxidim),
6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), 2- (2-chloro-4-methylsulfonyl-benzyl) -cyclohexane-1,3-dione (sulcotrione), 2- (2,4-dichloro-5-methylsulfonylamino-phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), methyl [[[[2- (4,6-dimethyl-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -benzoate (sulfometuron-methyl), N-phosphonomethyl-glycine-trimethylsulfonium (sulfosate), N- (4.6 -dimethoxy-pyrimidin-2-yl) -N '- (2-ethylsulfonyl) -imidazo [1,2-a] pyridine-3-sulfonamide (sulfosulfuron), 6-chloro-4-ethylamino-2-tert-butylamino- 1,3,5-triazine (terbuthylazine), 2-tert-butylamino -4-ethylamino-6-methylthio-1,3,5-triazine (terbutrin), 2-chloro-N- (2,6-dimethyl-phenyl ) -N (3-methoxy-2-thienyl-methyl) -acetamide (tenylchloro), methyl 2-difluoromethyl-5- (4,5-dihydro-thiazol-2-yl) -4- (2-methyl- propyl) -6-trifluoromethyl-pyridine-3-carboxylate (thiazopyr),
6- (6,7-dihydro-6,6-dimethyl-3H, 5H-pyrrol [2,1-c] -1,2,4-thiadiazol-3-ylidenoamino) -7-fluoro-
4- (2-propynyl) -2H-1,4-benzoxazin-3 (4H) -one (thidiazimin), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) - N '- (2-methoxy-carbonyl-thien-3-yl-sulfonyl) -urea (tifensulfuron-methyl), 2- (ethoxy-propyl) -3-hydroxy-5- (2,4,6-trimethyl-phenyl) ) -2-cyclohexen-1-one (tralcoxidim),
5- (2,3,3-trichloro-2-propenyl) diisopropylcarbamothioate (trialate), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- [ 2- (2-chloro-ethoxy) -phenylsulfonyl-urea] (triasulfuron), N-methyl-N (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2 -methoxycarbonyl-phenylsulfonyl) -urea (tribenuron-methyl), (3,5,6-trichloro) -pyridin-2-yl-oxy-acetic acid (triclopyr), 2- (3,5-dichloro-phenyl) -2 - (2,2,2-trichloroethyl) -oxyrane (tridiphane), sodium salt of
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N - [[(4,6-dimethoxy-2-pyrimidinyl) -amino] -carbonyl] -3- (2,2,2-trifluoro-ethoxy) -2-pyridinessulfonamide (trifloxysulfuron), 1-amino-2, 6-dinitro-N, N-dipropyl-4-trifluoromethyl-benzene (trifluralin), N- [4-dimethylamino-6- (2,2,2-trifluoro-ethoxy) -1,3,5-triazin-2- yl] -N '(2-methoxycarbonyl-phenylsulfonyl) -urea (triflusulfuron-methyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) -N' - (2- trifluoromethyl-phenylsulfonyl) -urea (tritosulfuron), N - [[(4,6-dimethoxy-2-pyrimidinyl) -amino] -carbonyl] -3- (N-methyl-N-methylsulfonyl-amino) -2-pyridinesulfonamide , 4- [4,5-dihydro-4-methyl-5-oxo- (3-trifluoromethyl) -1 H-1,
2.4- triazol-1-yl] -2 - [(ethylsulfonyl) amino] -5-fluoro-benzenocarbothioamide,
4-dichloroacetyl-1-oxa-4-aza-spiro [4,5] -decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrol [1,2-a] -pyrimidin -6 (2H) -one (BAS-145138),
4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 1-methylhexyl
5- chloro-quinoxalin-8-oxy-acetate (cloquintocet-mexila), a- (cyano-methoxy-amino) -phenylacetonitrile (ciometrinyl), 2,4-dichlorophenoxy-acetic acid (2,4-D),
2.2- dichloro-N- (2-oxo-2- (2-propenylamino) -ethyl) -N- (2-propenyl) -acetamide (DKA-24),
2.2- dichloro-N, N-di-2-propenyl-acetamide (dichlormide), N- (4-methyl-phenyl) -N'- (1-methyl-1-phenyl-ethyl) -urea (dymron), 4 , 6-dichloro-2-phenyl-pyrimidine (fenclorima), ethyl 1- (2,4-dichloro-phenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (fenclorazol-ethyl), phenylmethyl 2-chloro-4-trifluoromethyl-thiazol-5-carboxylate (flurazole),
4-chloro-N- (1,3-dioxolan-2-yl-methoxy) -a-trifluoro-acetophenone oxime (fluxophenime), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl-oxazolidine ( furilazole, MON-13900), ethyl
4.5- dihydro-5,5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl), (4-chloro-2-methyl-phenoxy) -acetic acid (MCPA), (±) -2- (4-chlorine -2-methylphenoxy) propanoic (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazol-3,5-dicarboxylate (mefenpir-diethyl), 2- dichloromethyl-2-methyl-1,3-dioxolane (MG-191), anhydrous 1,8-naphthalic, a- (1,3-dioxolan-2-yl-methoxymin) -phenylacetonitrile (oxabetrinyl), 2,2-dichloro -N (1,3-dioxolan-2-yl-methyl) -N- (2-propenyl) -acetamide (PPG-1292), 3-dichloroacetyl
-2,2,5-trimethyl-oxazolidine (R-29148), N-cyclopropyl-4 - [[(2-methoxy-5-methyl-benzoyl)
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-amino] -sulfonyl] -benzamide, N - [(4-methoxyacetylamino) -phenyl] -sulfonyl-2-methoxy-benzamide, and N - [(4-methylaminocarbonylamino) -phenyl] -sulfonyl-2-methoxy-benzamide.
[010] In one embodiment of the present invention, the herbicidally active compound is one or more selected from 2,4-D, bensulfurone, bentazone, bispiribaque-sodium, bromoxynil, cafenstrol, chloridazone, cletodim, clodinafope, dicamba, diflufenicano, phenoxaprope, florassulam, fluazifop, flufenacet, fluroxypyr, glufosinate, glyphosate, haloxifop, iodosulfuron, isoproturon, isoxaflutol, MCPA, MCPB, mecoprop, mesosulfuron, metamiphope, metsulfuron, picloram, trichloroxyl, picloxam, trichloroxan, pinoxadl alachlor, amicarbazone, atrazine, bromacila, carfentrazone-ethyl, chlorimuron-ethyl, clodinafop-propargyl, cyanazine, diclosulam, dimethenamide, S-dimethenamide, diuron, EPTC, phenoxaprope- (P) -ethyl, fentrazamide, flacbona, flacdona, flucarbamide flumetsulam, glufosinate-ammonium, glyphosate-isopropylammonium, imazamox, imazaquine, imazetapyr, isoxaflutol, mesotrione, metolachlor, S-metolachlor, metosulam, metribuzin , nicosulfuron, norflurazon, pendimethalin, propoxycarbazone-sodium, rimsulfuron, simazine, sulfometuron-methyl, sulcotrione, sulfentrazone, sulfosate, terbutilazine, tifensulfuron-methyl, trifluralin, 4- [4,5-di-hydro-4-methyl-4 oxo- (3-trifluoromethyl) -1H-1,2,4-triazol-1-yl] -2 - [(ethylsulfonyl) amino] -5-fluoro-benzenocarbothioamide, 1-methylhexyl 5-chloro-quinoxalin-8 -oxy-acetate (cloquintocet-mexila), ethyl 4,5-dihydro-5,
5-diphenyl-3-isoxazolcarboxylate (isoxadifen-ethyl), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazol-3,5-dicarboxylate (mefenpir-diethyl) , 4-dichloroacetyl-1-oxa-4-azospiro [4,5] -decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrole [1,2-a]
-pyrimidin-6 (2H) -one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 3-dichloroacetyl-5- (2 -furanyl) -2,2-dimethyl-oxazolidine (furilazole, MON-13900), and 3-dichloroacetyl-2,2,5-trimethyl-oxazolidine (R-29148).
[011] In one embodiment of the present invention, the herbicidal composition further comprises a surfactant and liquid or solid diluent. In a modalida
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13/58 of the present invention, the herbicidally active compound can be found in an amount of 0.01-1,000 parts by weight based on 1 part by weight of the uracil compound represented by formula 1. In another embodiment, the herbicidally compound active can be found in an amount of 0.02-500 parts by weight based on 1 part by weight of the uracil compound represented by formula 1. In yet another embodiment, the herbicidally active compound can be found in an amount of 0, 05-100 parts by weight based on 1 part by weight of the uracil compound represented by formula 1. In an embodiment of the present invention, said diluent or surfactant can be found in an amount of 0.1-99.9% by weight based on the total weight of the composition. In one embodiment of the present invention, the herbicidal composition is in the form of wettable powder, suspensions, emulsifiable concentrates, emulsions, microemulsions, soluble concentrates, dispersible concentrates, water-dispersible granules, granules, powder, suspension concentrates, water-floating granules or pills. The active ingredients further include at least one of the acetyl-CoA carboxylase (ACC) inhibitors, acetolactate synthase (ALS) inhibitors, amides, auxin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, enolpyruvylshyme-3 inhibitors -phosphate synthase (ESPS), glutamine synthase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protoporphyrinogen IX oxidase inhibitors, photosynthesis inhibitors, synergistic agents, growth substances, cell wall biosynthesis inhibitors and other known herbicides. In one embodiment of the present invention, the herbicidal composition is non-selective. In one embodiment of the present invention, the herbicidal composition is used in dry field or paddy farming, and in another embodiment of the present invention, the herbicidal composition is used in paddy farming.
[012] Agrochemical formulations contain the herbicidal composition of the present
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14/58 is available in an amount of 0.1-95% by weight and preferably 0.5-90% by weight.
[013] These formulations are produced in a known way, for example, by mixing the active ingredients with extenders, that is, liquid solvents and / or solid vehicles, optionally, with the use of surfactants, that is, emulsifying agents and / or dispersing agents, and / or foaming agents.
[014] The surfactant that is used in the present invention is an amphiphilic material having a high surfactant activity and containing both lipophilic and hydrophilic molecules. It has excellent cleaning, dispersing, emulsifying, solubilizing, wettability, sterilizing, foaming, and penetrating capabilities, and it also acts to wet, disintegrate, disperse, and emulsify the active ingredients, so that the effects of the active ingredients are displayed. efficiently. The surfactant can be one or a mixture of two or more selected from anionic surfactants, including a sodium or calcium salt of a sulfonate, such as (C8-C12) benzene sulfonate, alkyl (C3-C6) naphthalene sulfonate, dialkyl (C3-C6) naphthalene sulfonate, dialkyl (C8-C12) sulfosuccinate, lignin sulfonate, naphthalene sulfosuccinate formalin concentrates, (C8-C12) naphthalene sulfonate formalin concentrates, or polyoxyethylenealkyl (C8-C12) phenyl sulfonate salt sodium or calcium sulfate, such as alkyl (Cs-C12) sulfate, polyoxyethylenealkyl (C8-C12) sulfate, or polyoxyethylenealkyl (C8-C12) phenyl sulfate, or a sodium or calcium salt of a succinate, such as polyoxyalkylene succinate, and non-ionic surfactants, such as polyoxyethylenealkyl (C8-C12) ether polymers, polyoxyethylenealkyl (C8-C12) phenyl ether, or polyoxyethylenealkyl (C8-C12) phenyl.
[015] The diluent that is used in the present invention can be either a solid diluent or a liquid diluent. For a solid thinner, it is particularly preferable to use one that has a high water absorption capacity to prepare the
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15/58 wettable powder. For a liquid diluent, one that is stable without phase separation of a solvent even at 0 C is preferred. Examples of the liquid diluent that can be used in the present invention include water, toluene, xylene, petroleum ether, vegetable oil, acetone , methyl ethyl ketone, cyclohexanone, acid anhydride, acetonitrile, acetophenone, amyl acetate, 2-butanone, butylene carbonate, chlorobenzene, cyclohexane, cyclohexanol, acetic acid alkyl ester, alcohol diacetone,
1,2-dichloropropane, diethanolamine, p-diethylbenzene, diethylene glycol, diethylene glycol abietate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N, N-dimethylformamide, dimethyl sulfoxide, 1,4-dioxane, dipropyl dipropylene glycol methyl ether, dipropylene glycol dibenzoate, diproxitol, alkyl pyrrolidone, ethyl acetate, 2-ethylhexanol, ethylene carbonate, 1,1,1-trichloroethane, 2-heptanone, .alpha.-pinene, D-limonene, ethyl lactate, ethylene glycol, ethylene glycol butyl ether, ethylene glycol methyl ether, gamma-butyrolactone, glycerol, glycerol acetate, glycerol diacetate, glycerol triacetate, hexadecane, hexylene glycol, isoamyl acetate, isobornyl acetate, isoornyl acetate, isoornyl acetate, isoornyl acetate, isoornyl acetate, iso , isopropyl myristate, lactic acid, laurylamine, mesityl oxide, methoxypropanol, methyl isoamyl ketone, methyl isobutyl ketone, methyl laurate, methyl octanoate, methyl oleate, methylene chloride, m-xi lene, n-hexane, n-octylamine, octadecanoic acid, octylamine acetate, oleic acid, oleylamine, o-xylene, phenol, polyethylene glycol (PEG), propionic acid, propyl lactate, propylene carbonate, propylene glycol, propylene glycol methyl ether, p-xylene, triethyl phosphate, triethylene glycol, xylenesulfonic acid, paraffin, mineral oil, trichlorethylene, perchlorethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol methyl ether, diethylene glycol methyl ether, methanol, ethanol, high alcohol and isopropanol molecular, for example, amyl alcohol, tetrahydrofurfuryl alcohol, hexanol, octanol, ethylene glycol, propylene glycol and glycerol, N-methyl-2-pyrrolidone or the like. The solid diluent can be talc, titanium dioxide, agalmatolite clay, silica, atapulgite clay, diatomite, limestone, calcium carbonate, bentonite, montmorillon
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16/58 nita of calcium, cottonseed bark, wheat bran, soy flour, pumice stone, wood flour, nutshell, lignin, and the like.
[016] If water is used as an extender, organic solvents can also be used as auxiliary solvents. The liquid solvents that are most suitable are: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example, petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol, as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethylsulfoxide and water.
[017] Suitable solid vehicles are, for example, ammonium salts and natural soil minerals, such as kaolin, clays, talc, chalk, quartz, atapulgite, montmorillonite or diatomaceous earth and synthetic soil minerals, such as finely divided silica , alumina and silicates. Solid vehicles suitable for granules are, for example, fractionated or crushed natural rocks, such as calcite, marble, pumice, sepiolite and dolomite, or other synthetic granules of organic and inorganic bran, and granules of organic material, such as saw, coconut shells, corn cobs and tobacco stalks. Suitable emulsifiers and / or foaming agents are, for example, nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol esters, for example, alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolyzed. Suitable dispersants are, for example, lignin-sulfite and methylcellulose residue liquors. Adhesives, such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules, or latexes, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, or other natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids can be used in formulations .
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Other additives can be mineral and vegetable oils. It is possible to use dyes, such as inorganic pigments, for example, iron oxide, titanium oxide, and Prussian Blue, and organic dyes, such as alizarin dyes, azo dyes and phthalocyanine metal dyes, and traces of nutrients, such as such as iron, manganese, boron, copper, cobalt, molybdenum and zinc salts.
[018] A protective agent that can be used in the present invention is one or more selected from the group consisting of benoxacor, cloquintocet, ciometrinil, dichloromid, dicyclonon, diethylate, fenclorazole, fenclorima, flurazole, fluxofenima, furilazol, isoxadifen, mefenpir, mefenate, naphthalic anhydride, 2,2,5-trimethyl-3- (dichloroacetyl) -1,3-oxazolidine, 4- (dichloroacetyl) -1 -oxa-4-azospiro [4,5] decane and oxabetrinyl.
[019] The herbicidally active compounds, described above, include a number of known protective agents or antidotes capable of antagonizing the harmful effect of the herbicide on plant species. It is known that 2,4-dichlorophenoxy-acetic acid (2,4-D) and its derivatives, (4-chloro-2-methylphenoxy) acetic acid (MCPA), (±) -2- (4-chlorine) -2-methylphenoxy) propanoic (mecoprop) are herbicidally active compounds that act as protective agents or antidotes. Compounds that act as protective agents or antidotes are herbicidally active compounds that can be included in the herbicidal composition of the present invention, and these compounds neutralize the harmful effect of the compounds on practically completed plant species without adversely affecting the herbicidal activity of weeds. . At least one of said protective agents or antidotes can be used in a mixture with the herbicidal composition of the present invention.
[020] As used here, the term dry field agriculture refers to the cultivation of crops, including, but not limited to, potatoes, sweet potatoes, carrots, Chinese cabbage, radishes, corn, watermelon, lettuce, sesame or perilla leaves, grains, Japanese Perilla
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18/58 single, sesame, red pepper, cucumbers, eggplants and cabbage. As used here, the term rice paddy farming means agriculture that is carried out by irrigating water, and typical examples of this include rice cultivation. As used here, the term non-selective herbicide refers to one that kills all plants, with no distinction between crops and weeds. Specifically, the non-selective herbicide refers to one that can kill all plants that grow not only in gardens and rice fields, but also in places where crops are not grown, including fallow areas, the bank around a rice field and a furrow.
[021] The herbicidal composition of the present invention can be used in a mixture with other known herbicides or in a formulation thereof. The active compounds in the herbicidal composition of the present invention are applied in the form of ready-made mixtures. However, the active compounds can also be formulated individually and mixed using, that is, applied in the form of tank mixtures. The composition of the present invention can be mixed with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellents, growth substances, plant nutrients and agents that improve soil structure. For specific application purposes, especially when applied post-emergence, it may be more advantageous to incorporate, in the formulations, vegetable or mineral oils that are tolerated by plants (for example, the commercial product Rako Binol) or ammonium salts, for example, ammonium sulfate or ammonium thiocyanate, as well as other additives.
[022] The herbicidal composition of the present invention can be used, such as in the form of its formulations or in the use of forms prepared by dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. It is used in the usual way, for example, for irrigation, spraying, atomization, crowding or broadcasting.
[023] The herbicidal composition of the present invention can include one or more
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19/58 compounds represented by formula 1, as active ingredients. In addition, the uracil compound can be a free base of the compound represented by formula 1 or an agrochemically acceptable salt thereof. Furthermore, because one or more chiral carbons can exist in the molecular structure of the compound represented by formula 1, the definition of the uracil compound of the present invention includes enantiomers, diasteromers, simple racemates and the like.
[024] Examples of an agrochemically acceptable salt of the compound represented by formula 1 include, metal salts, salts with organic bases, salts with organic acids, salts with basic or acidic amino acids and the like. Metal salts include, for example, alkali metal salts, such as sodium or potassium salts, alkaline earth metal salts, such as magnesium or barium salts, aluminum salts and the like. Salts with organic bases include, for example, salts with trimethylamine, triethylamine, pyridine, picoline, 2,6-lutidine, ethanolamine, diethanolamine, triethanolamine, cyclohexylamine, dicyclohexylamine, MMdibenzylethylenediamine and the like. Examples of salts with inorganic acids include salts with hydrochloric acid, hydrobromic acid, nitric acid, sulfuric acid, phosphoric acid, etc. Examples of salts with organic acids include salts with formic acid, acetic acid, trifluoroacetic acid, phthalic acid, furamic acid, oxalic acid, tartaric acid, maleic acid, citric acid, succinic acid, methanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid etc. . Examples of salts with basic amino acids include salts with arginine, lysine, ornithine, etc. Examples of salts with acidic amino acids include salts with aspartic acid, glutamic acid, etc.
[025] According to the invention, it is possible to treat all plants and parts of plants, with the herbicidal composition of the present invention. The term plants should be understood here as all plants and plant populations, such as desired and unwanted wild plants or plant species (including natural plant species). Plant species can be plants that can be obtained by
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20/58 conventional and optimized methods of reproduction or by genetic engineering and biotechnological methods or a combination of these methods, including transgenic plants and including plant varieties that may or may not be protected by varietal property rights. Plant parts should be understood as all parts above ground and below ground and plant organs, such as buds, leaves, flowers and roots, examples that can be mentioned as being leaves, thorns, stems, trunks, flowers, fruit structure, fruits and seeds and also roots, tubers and rhizomes. Plant parts also include material for vegetative and generative propagation, for example, seedlings, tubers, rhizomes, cuttings and seeds.
[026] The treatment of plants and parts of plants, with the herbicidal composition of the present invention is carried out directly or by action on their environment, habitat or storage area according to the usual treatment methods, for example, by immersion, spraying , evaporation, atomization, broadcasting, brushing and, in the case of propagating material, in particular in the case of seeds, still by the coating of one or multilayer (s). Among the plants obtained by genetic engineering or biotechnological methods or combinations of these methods, emphasis is given to those plants that tolerate the so-called 4HPPD, EPSP and / or PPO inhibitors, such as, for example, Acuron plants.
[027] The herbicidal composition according to the invention can be applied to the following plants. However, the use of combinations of the active compound according to the invention is in no way restricted to these genera, but also extends in the same way to other plants:
[028] Dicotyledonous weeds: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erysimum, Euphorbia, Euphia , Galinsoga, Galium, Hibiscus, Ipomoea, Kochia, Lamium, Le
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21/58 pidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchum , Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, and Xanthium;
[029] Dicotyledonous cultures: Arachis, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, Pisum, Solanum and Vicia;
[030] Monocotyledonous weeds: Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrisis, Eroch , Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, and Sorghum;
[031] monocotyledon cultures: Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum, and Zea.
[032] The herbicidal compositions according to the invention can be used in conventional cultivation methods (strip cultivation with suitable strip width) and in plantation cultivation (for example, vines, fruit, citrus), as well as industrial plants and tracing systems on roads and squares, but also to deal with straw and the minimum tillage method. They are also suitable as burners (to kill foliage, for example, in potatoes) or as defoliants (for example, in cotton).
[033] They are also suitable for use in fallow areas. Other areas of use are in nurseries, forests, meadows and in the cultivation of ornamental plants. The herbicidal composition according to the invention can be converted into common formulations, such as solutions, emulsions, wettable powders, suspensions, powders, fillers, pastes, soluble powders, granules, suspension concentrates
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22/58 are emulsion, natural and synthetic materials impregnated with active compound, and very thin capsules made of polymeric substances.
[034] The herbicidal composition according to the invention can be applied before and after the plants sprout, that is, pre-sprouting and post-sprouting. It can also be incorporated into the soil before sowing. The good herbicidal activity of the herbicidal composition of the present invention can be seen from the following examples. While the individual active compounds have weak points in relation to herbicidal activity, the combinations, without exception, exhibit a very good activity against weeds that exceeds a simple additive effect. A synergistic effect on herbicides is always present when the herbicidal activity of the active combination exceeds the activity of the active compounds when applied individually.
[035] The expected activity for a given combination of two herbicides can be calculated as shown in the following equation 1 (COLBY, S. R., Calculating synergistic and antagonistic responses of herbicide combinations, Weeds 15, pages 20-22, 1967):
Equation 1
E = X + Y - (XxY / 100)
In equation 1, [036] X is the% damage per uracil compound (a) of formula 1 at the application rate of p kg / ha; Y is the% of damage by conventional herbicidal compound (b) at the application rate of q kg / ha; and E is the expected damage caused by compounds (a) and (b) at an application rate of p and q kg / ha.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS [037] In the following, the present invention will be described further with reference to the examples. It should be understood, however, that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention.
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23/58 [038] In the following examples, the compounds described in Korean Patent No. Q 1,103,840 were mixed with other herbicidally active compounds, and the effects of that mixture were examined.
Formula 1
i ch 3
In Formula 1, [039] R 1 and R 2 are the same or different and represent a hydrogen atom or a C1-C6 alkyl group; R 3 represents a hydrogen atom, a hydroxyl group, a C1-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group, a C1-C8 alkoxy group, a C1-C6 haloalkyl group, a C2 group -C6 haloalkenyl, a C1-C6 alkoxy C1-C6 alkyl group, or a C6-C10 aryl C1-C6 alkoxy group; R 4 represents a hydrogen atom, a C1-C6 alkyl group, a C1-C6 haloalkyl group or a C1-C6 alkoxycarbonyl C1-C6 alkyl group; R 5 represents a hydrogen atom, a C1-C6 alkyl group, a C1-C6 alkoxy group, a C2-C6 haloalkyl group, a C2-C6 alkenyl group, a C2-C6 haloalkenyl group, a C2-C6 alkynyl group, a C1-C6 alkoxycarbonyl group, a C1-C6 alkyl group, a C6-C10 aryl C1-C6 alkyl group or a C6-C10 aryl C1-C6 alkoxy group; X represents O, S, SO, SO2, NH or N (C 1 -C 6 alkyl); Y represents a C1-C6 alkylene group or a C1-C6 haloalkylene group; W represents O, S, NH or N (C 1 -C 6 alkyl); and Z represents a halogen atom, a cyan group, CONH2 or CSNH2.
[040] Preferably, the uracil compound represented by formula 1 is a uracil compound, where R 1 and R 2 are the same or different and represent a hydrogen atom or a methyl group; R 3 represents a hydrogen atom, a
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Hydroxyl group, methyl group, methoxy group or benzyloxy group; R 4 represents a hydrogen atom or a methyl group; R 5 represents a hydrogen atom, a methyl group, an ethyl group, an n-propyl group, an n-butyl group, a methoxy group, an ally group, a propargyl group, a benzyl group, a benzyloxy group, or a methoxycarbonylmethyl group; X represents O, S, SO2, or NH; Y represents CH2, CH (CH3), CH2CH2, CH2CH2CH2, or CH (CH2F); W represents O, or NH; and Z represents a chlorine atom, a cyano group, or CSNH2.
[041] More preferably, the uracil compound represented by formula 1 is a uracil compound, wherein R 1 and R 2 are the same or different and represent a hydrogen atom or a methyl group; R 3 represents a hydrogen atom, a hydroxyl group, a methyl group, or a methoxy group; R 4 represents a hydrogen atom; R 5 represents a hydrogen atom, a methyl group, an ethyl group, an n-butyl group, an allyl group, a propargyl group, or CH2CO2CH3; X represents O, S, or NH; Y represents CH2, CH2CH2, or CH (CH2F); W represents O; and Z represents a chlorine atom.
[042] Among the compounds represented by formula 1, according to the present invention, the particularly preferred compounds are the following:
[043] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound 1);
[044] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} methoxyamino] propionic (compound 4);
[045] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} benzyloxyamino] propionic (compound 5);
[046] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} hydroxyamino] propionic (with
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25/58 rank 6);
[047] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] -4-fluorobutyric (compound 8);
[048] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] butyric (compound 9);
[049] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] -2-methylpropionic (compound 10);
[050] 4 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] butyric (compound 11);
[051] 5 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1-oxopropyl} amino] pentanoic (compound 12);
[052] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1-oxoethyl} amino] propionic (compound 13);
[053] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenylamino] -1-oxopropyl} amino] propionic (compound
15);
[054] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxoethyl} methylamino] propionic (compound
16);
[055] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1-oxopropyl} amino] propionic (compound 18);
[056] benzyl acid ester 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound
20);
[057] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-tri) acid n-propyl ester
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26/58 fluoromethyl-1 (2H) -pyrimidinyl) -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound 21);
[058] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] propionyloxy acetic (compound 22);
[059] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) - n-butyl ester pyrimidinyl) -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound
23);
[060] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) ethyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound 24);
[061] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) allyl ester] -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound 25);
[062] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) acid propargyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound 26);
[063] 4 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) ethyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] butyric (compound 28);
[064] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenylthio] -1 -oxopropyl} amino] propionic (compound 36);
[065] 3 - [{2- [2-cyano-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) methyl ester -4-fluorophenoxy] -1 -oxopropyl} amino] propionic (compound 46);
[066] 3 - [{2- [2-aminothiocarbonyl-5- (3,6-dihydro-3-methyl-2,6dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -4 acid methyl ester -4 -fluorophenoxy] -1-oxopropyl} amino] propiponic (compound 52); and [067] 3 - [{2- [2-chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl acid methyl ester ) -4-fluorophenylsulfonyl] -1 -oxopropyl} amino] propionic (compound 61);
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27/58 [068] The chemical structures of the uracil compounds described above are summarized in Table 1 below.
Table 1
i ch 3
N s | R 1 | R 2 Γ R 3 IR 4 I R 5 I X I Y I W | z 1 | Me | Η Γ H I Η I Me I O | ch 2 I O | Cl 2 | Me | Η Γ H | Me | Me I o | ch 2 I O | Cl 3 | Me | Η Γ H I Η I H I o | ch 2 I Ο I Cl 4 | Me | Η Γ OMe I Η I Me I o | ch 2 I O | Cl 5 | Me | Η Γ OBn I H | Me I o | ch 2 I Ο I Cl 6 | Me | Η Γ OH I H | Me I o | ch 2 I O | Cl 7 | Me | Η Γ H I H | Pr I o | CHMe I O | Cl 8 | Me | Η Γ H I H | Et I o | CHCH 2 F I O | Cl 9 | Me | Η Γ H I H | Me I o | CHMe I O | Cl 10 | Me | Η Γ H | Me | Me I o | ch 2 I Ο I Cl 11 | Me | Η Γ H I Η I Me I o | ch 2 ch 2 I O | Cl 12 | Me | Η Γ H I Η I Me I o | ch 2 ch 2 ch 2 I O | Cl 13 | H | Η Γ H I H | Me I o | ch 2 I O | Cl 14 | H | Η Γ H I H | H I o | ch 2 I O | Cl 15 | Me | Η Γ H I H | Me I nh | ch 2 I Ο I Cl 16 | H | Η Γ Me I H | Me I o | ch 2 I O | Cl 17 | Me | Η Γ H I H | n-Pr I o | ch 2 I Ο I Cl 18 | Me | Me | H I H | Me I o | ch 2 I o | Cl 19 | Me | Me | H I H | Et I o | ch 2 I o | Cl 20 | Me | Η Γ H I H | Bn I o | ch 2 I o | Cl 21 | Me | Η Γ H I H | n-Pr I o | ch 2 I o | Cl 22 | Me | Η Γ H I H | CH 2 CO 2 Me I o | ch 2 I o | Cl 23 | Me | Η Γ H I H | n-Bu I o | ch 2 I o | Cl 24 | Me | Η Γ H I H | Et I o | ch 2 I o | Cl 25 | Me | Η Γ H I H | Alila I o | ch 2 I o | Cl 26 | Me | Η Γ H I H | Propargila I o | ch 2 I o | Cl 27 | Me | Me [” H I H | Alila I o | NH I o | Cl 28 | Me | Η Γ H I H | Et I o | CH 2 CH 2 I o | Cl 29 | Me | Η Γ Me I H | Me I o | ch 2 I o | Cl 30 | Me | Η Γ Me I H | H I o | ch 2 I o | Cl 31 | Me | Me | H I H | H I o | ch 2 I o | Cl
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| 32 | H | H | H I Η I Et I O | ch 2 I O I ci 133 | Me 1 Η 1 H | Me | Me I nh | CHMe I O I ci 134 | Me | H CH 2 F I Η I Me I o | ch 2 I O I ci 135 | Me | H Alila I Η I Me I o | ch 2 I O I Cl 136 | Me | H | H I H | Me I s | ch 2 I O I Cl 137 | Me | H | H I H | Et I s | ch 2 I O I Cl 138 | Me | H OMe I H | Me I s | ch 2 I O I Cl 139 | Me | H | H I H | Me I s | CHMe I O I Cl 140 | Me | H | H | Me | Et I s | CHMe I O I Cl 141 | Me | H | H I Η I Et I o | CHMe I O I Cl 142 I Me I Η I H I Η I Me I nh | ch 2 I o I Cl 143 | Me | H | Me I H | Me I nh | ch 2 I o I Cl 144 | Me | H | OMe I H | Me I nh | ch 2 I o I Cl 145 | Me | H | OMe I H | Et I o | ch 2 I o I ci 146 | Me | H | H I H | Me I o | ch 2 I o | CN 147 | Me | H | H I H | Et I o | ch 2 I o CN 148 | Me | H | H I H | n-pr I o | ch 2 I o CN 149 | Me | H | H I H | Me I o | ch 2 I o CONH 2 150 | Me I Η I H I H | Et I o | ch 2 I o ccnh 2 51 | Me | H | H I H | n-pr I o | ch 2 I o ccnh 2 152 | Me I Η I H I H | Me I o | ch 2 I o csnh 2 153 | Me | H | H I H | Et I o | ch 2 I o csnh 2 154 | Me | H | H I H | n-pr I o | ch 2 I o csnh 2 155 | Me | H | H I H | Me I o | ch 2 | NH I Cl 156 | Me | H | H I H | Et I o | ch 2 | NH I Cl 157 | Me | H | H I H | OMe I o | ch 2 | NH I Cl 158 | Me | H | H I H | OH I o | ch 2 | NH I Cl 159 | Me | H | H I H | OBn I o | ch 2 | NH I Cl 160 | Me | H | H I H | Me I so | ch 2 I o I Cl 61 | Me | H | H I H | Me | SO 2 | ch 2 I o I Cl | Me: methyl group; Et: ethyl group; n-Pr: propyl group; Bu: butyl group; Bn: benzyl group.
[069] To test herbicidal activities, (1) in the case of non-selective herbicidal compositions, weeds in the growing phase (30-40 cm) in fallow areas and orchards were treated with compositions containing uracil compounds and herbicide compounds active. (2) In the case of dry field agriculture, weeds in the initial growing state (5 cm or less) in wheat and corn fields were treated with compositions containing uracil compounds and herbicidally active compounds. (3) In the case of paddy farming, weeds in the rice fields were treated with compositions containing
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29/58 uracil posts and herbicidally active compounds 15 days after rice transplantation.
[070] Herbicidal activities were visually evaluated by comparing plant mortality with untreated control groups 20 days after treatment with the compositions.
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilontheophrasti Aeschynomene indica Xanthium spinosum Compound 1 4 00171811Compound 1 8 55454539Compound 1 16 1720606052Glyphosate 150 1288911Glyphosate 300 2318272230Glyphosate 600 4846594764Compound 1 + Glyphosate 4 + 600 53 48 49 46 70 66 63 57 78 68 Compound 1 + Glyphosate 8 + 300 50 27 44 22 95 60 91 57 88 57 Compound 1 + Glyphosate 16 + 150 36 27 36 26 68 63 72 64 67 57
[071] However, if the current damage exceeds the calculated value, the activity of the combination is superadditive. The expected activity for a given combination of two herbicides can be calculated using equation 1 above.
Example 1: Non-selective herbicidal composition [072] Weeds in the growing phase (30-40 cm) in fallow areas and orchards were treated with non-selective herbicidal compositions containing uracil compounds and herbicidally active compounds.
Experimental Example [073] Tables 2 to 29 below show the plant mortality (herbicidal activities) obtained when Echinochloa crus, Digitaria sanguinalis, Abutilon theophrasti, Aeschynomene indica and Xanthium spinosum were treated with the indicated amounts of uracil compounds, non-selective herbicides , and mixtures of herbicide / uracil compound. When the measured values are higher than the calculated values, the test materials have significant herbicidal activities. The two left columns for each gram in the tables below indicate the values
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30/58 measured mortality, and the right column indicates the calculated mortality values.
Table 2
Table 3
Component g / ha Data (measured value / calculated value) [074] ’5] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Compound 1 4 00171811Compound 1 8 55454539Compound 1 16 1720606052Glufosinate 75 15117513Glufosinate 150 2927251825Glufosinate 300 6057494656Compound 1 + Glufosinate 4 +300 64 60 66 57 67 58 60 56 64 61 Compound 1 + Glufosinate 8 +150 56 33 53 30 89 58 86 55 84 54 Compound 1 + Glufosinate 16 +75 39 29 36 29 73 63 70 62 66 58
Table 4
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0011262136 8 5538524236 16 1016516956Glyphosate 150 1288911Glyphosate 300 2318272230Glyphosate 600 4846594764Compound 36 + Glyphosate 4 +600 57 48 56 46 68 64 66 61 76 72 Compound 36 + Glyphosate 8 +300 48 27 44 22 87 54 94 62 92 59 Compound 36 + Glyphosate 16 +150 25 20 29 23 63 55 78 72 64 61
Table 5
Component g / ha Data (measured value / calculated value) [078] 79] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0011262136 8 5538524236 16 1016516956Glufosinate 75 15117513Glufosinate 150 2927251825Glufosinate 300 6057494656Compound 36 + Glufosinate 4 +300 63 60 66 57 62 55 70 60 71 65 Compound 36 + 8 + 56 33 54 30 84 53 93 61 90 57
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Glufosinate 150 Compound 36 + Glufosinate 16 +75 26 23 28 25 61 54 81 71 69 62
Table 6
Component g / ha Data (measured value / calculated value) [080] 81] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Fenoxaprop 25 1313000Fenoxaprop 50 3132000Fenoxaprope 100 6564000Compound 36 +Fenoxaprope 20 +100 79 71 79 71 66 58 63 56 57 51 Compound 36 +Fenoxaprope 40 +50 90 56 95 61 100 100 100 100 100 90 Compound 36 +Fenoxaprope 80 +25 74 66 80 75 100 100 100 100 100 100
Tabe a 7
Component g / ha Data (measured value / calculated value) [082] 83] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Clodinafope 7.5 1210000Clodinafope 15 2521000Clodinafope 30 5350000Compound 36 +Clodinafope 20 +30 64 61 68 60 61 58 61 56 60 51 Compound 36 +Clodinafope 40 +15 84 52 83 55 100 100 100 100 100 90 Compound 36 +Clodinafope 80 +7.5 71 66 83 74 100 100 100 100 100 100
Table 8
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Fluazifope 50 109000Fluazifope 100 2621000Fluazifope 200 6152000Compound 36 +Fluazifope 20 +200 77 68 71 61 68 58 66 56 54 51 Compound 36 +Fluazifope 40 +100 83 53 84 55 100 100 100 100 100 90 Compound 36 +Fluazifope 80 + 50 75 65 82 73 100 100 100 100 100 100
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Table 9
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Haloxifope 12.5 1114000Haloxifope 25 2829000Haloxifope 50 5857000Compound 36 +Haloxifope 20 + 50 74 65 72 65 64 58 60 56 54 51 Compound 36 +Haloxifope 40 + 25 88 54 89 59 100 100 100 100 100 90 Compound 36 +Haloxifope 80 +12.5 75 65 85 75 100 100 100 100 100 100
Table 10
Component g / ha Data (measured value / calculated value) [088] 89] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Metamifope 25 1111000Metamifope 50 2623000Metamifope 100 5748000Compound 36 + Metamifope 20 +100 68 64 65 58 67 58 65 56 54 51 Compound 36 + Metamifope 40 + 50 84 53 88 56 100 100 100 100 100 90 Compound 36 + Metamifope 80 + 25 68 65 78 74 100 100 100 100 100 100
Table 11
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Pinoxadena 6.25 1012000Pinoxadena 12.5 2926000Pinoxadena 25 6357000Compound 36 + Pinoxadena 20 + 25 72 69 72 65 62 58 62 56 61 51 Compound 36 + Pinoxadena 40 + 12.5 85 55 90 57 100 100 100 100 100 90 Compound 36 + Pinoxadena 80 + 6.25 73 65 82 74 100 100 100 100 100 100
________Table 12 | Component | g / ha | Data (measured value / calculated value)
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Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Cletodim 25 116000Cletodim 50 3119000Cletodim 100 6545000Compound 36 + Cletodim 20 +100 80 71 66 56 61 58 62 56 61 51 Compound 36 + Cletodim 40 + 50 88 56 84 53 100 100 100 100 100 90 Compound 36 + Cletodim 80 + 25 69 65 82 73 100 100 100 100 100 100
Table 13
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 20 171958565136 40 37431001009036 80 6171100100100Tralcoxidim 25 108000Tralcoxidim 50 2421000Tralcoxidim 100 5647000Compound 36 +Tralcoxidim 20 +100 69 64 64 57 66 58 66 56 60 51 Compound 36 +Tralcoxidim 40 + 50 80 52 83 54 100 100 100 100 100 90 Compound 36 +Tralcoxidim 80 + 25 69 65 81 73 100 100 100 100 100 100
Table 14
Component g / ha Data (measured value / calculated value) [096] > 7] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0015192436 8 5535465936 16 1215476179Imazetapir 25 11119119Imazetapir 50 2626242520Imazetapir 100 5362585447Compound 36 + Imazetapir 4 +100 56 53 65 62 67 64 72 63 68 60 Compound 36 + Imazetapir 8 +50 51 29 52 30 78 51 95 60 91 67 Compound 36 + Imazetapir 16 +25 31 21 28 24 55 51 69 65 86 81
Table 15
Component g / ha Data (measured value / calculated value) [098] '9] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Compouind 36 4 0 1 - 0 Ί - 15 1 - 19 1 - 24 | -
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36 8 5535465936 16 1215476179Trifloxysulfuron 1.25 8812913Trifloxysulfuron 2.5 2426282530Trifloxysulfuron 5 5651615862Compound 36 + Trifloxysulfuron 4 + 5 59 56 55 51 75 67 73 66 75 71 Compound 36 + Trifloxysulfuron 8 +2.5 50 28 54 29 83 53 91 60 96 71 Compound 36 + Trifloxysulfuron 16 +1.25 26 19 29 22 60 53 69 65 90 81
Table 16
Component g / ha Data (measured value / calculated value) [0100] > 1] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0015192436 8 5535465936 16 1215476179Bispiribaque-sodium 7.5 6816610Bispiribaque-sodium 15 2320312327Bispiribaque-sodium 30 4547624958Compound 36 + Bispiribaque-sodium 4 +30 57 45 64 47 75 68 65 59 75 68 Compound 36 + Bispiribaque-sodium 8 +15 81 26 81 24 85 55 86 58 95 70 Compound 36 + Bispiribaque-sodium 16 +7.5 69 18 72 22 63 55 70 64 85 81
Table 17
Component g / ha Data (measured value / calculated value) [0102] 03] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 10154565702,4-D 100 0077102,4-D) 200 002124222,4-D) 400 00475150Compound 36 + 4 + 6 0 3 0 65 52 63 61 67 63 2,4-D 400 Compound 36 + 8 + 10 5 15 10 75 44 91 58 95 61 2,4-D 200Compound 36 + 16 + 18 10 19 15 60 49 74 67 89 73 2,4-D 100
Table 18
Component g / ha Data (measured value / calculated value) [0104] 05] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0 - 0 - 10 - 20 - 25 - 36 8 5 - 10 - 30 - 45 - 50 - 36 16 10 - 15 - 45 - 65 - 70 - Dicamba 75 0 - 0 - 9 - 7 - 13 -
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Dicamba 150 0 - 0 - 20 - 23 - 29 - Dicamba 300 0 - 0 - 46 - 51 - 62 - Compound 36 + Dicamba 4 + 300 10 0 7 0 64 51 64 61 75 72 Compound 36 + Dicamba 8 + 150 21 5 22 10 79 44 91 57 90 65 Compound 36 + Dicamba 16 + 75 20 10 21 15 54 50 72 68 84 74
Table 19
Component g / ha Data (measured value / calculated value) [0106] 07] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570Picloram 25 00999Picloram 50 00282126Picloram 100 00655256Compound 36 + Picloram 4 +100 7 0 8 0 77 69 70 62 70 67 Compound 36 + Picloram 8 + 50 21 5 22 10 85 49 86 57 90 63 Compound 36 + Picloram 16 +25 18 10 22 15 56 50 71 68 88 73
Table 20
Component g / ha Data (measured value / calculated value) [0108] 09] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570Fluroxypyr 50 009137Fluroxypyr 100 00262723Fluroxypyr 200 00536354Compound 36 + Fluroxypyr 4 +200 5 0 7 0 69 58 76 70 71 66 Compound 36 + Fluroxypyr 8 +100 22 5 22 10 82 48 92 60 90 62 Compound 36 + Fluroxypyr 16 +50 20 10 19 15 55 50 69 70 80 72
Table 21
Component g / ha Data (measured value / calculated value) [0110] 11] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570Triclopir 125 0011913Triclopir 250 00232630Triclopir 500 0054585936 4 + 9 0 10 0 67 59 69 66 74 69
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+ Triclopir 500 Compound 36 + Triclopir 8 +250 22 5 21 10 82 46 85 59 88 65 Compound 36 + Triclopir 16 +125 16 10 19 15 60 51 74 68 80 74
Table 22
Component g / ha Data (measured value / calculated value) [0112] 13] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570MCPA 75 0011118MCPA 150 00322425MCPA 300 00645859Compound 36 + MCPA 4 + 300 5 0 3 0 76 68 76 66 77 69 Compound 36 + MCPA 8 + 150 22 5 22 10 86 52 85 58 88 62 Compound 36 + MCPA 16 + 75 15 10 20 15 63 51 69 69 83 72
Table 23
Component g / ha Data (measured value / calculated value) [0114] 15] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570Mecoprop 200 001489Mecoprop 400 00292419Mecoprop 800 00645545Compound 36 + Mecoprop 4 +800 6 0 4 0 78 68 73 64 64 59 Compound 36 + Mecoprop 8 +400 21 5 21 10 83 50 92 58 85 59 Compound 36 + Mecoprop 16 +200 19 10 19 15 58 52 69 68 80 73
Table 24
Component g / ha Data (measured value / calculated value) [0116] 7] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570Quincloraque 50 13691011Quincloraque 100 2621262729Quincloraque 200 5549575762Compound 36 + 4 + 66 55 55 49 70 61 75 66 80 72 Quincloraque 200Compound 36 + 8 + 55 29 50 28 80 48 88 60 92 65 Quincloraque 100
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Compound 36 + Quincloraque 16 +50 30 21 35 20 60 50 76 69 82 73 Table 25 Component g / ha Data (measured value / calculated value) [0118] 19] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0010202536 8 51030455036 16 1015456570MCPB 75 912111312MCPB 150 2725223227MCPB 300 5756526458Compound 36 + MCPB 4 +300 62 57 59 56 73 57 83 71 75 69 Compound 36 + MCPB 8 +150 55 30 52 33 80 45 88 63 90 64 Compound 36 + MCPB 16 +75 37 18 28 25 80 51 84 70 74 73
Table 26
Component g / ha Data (measured value / calculated value) [0120] 21] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0027282036 8 5554544836 16 2014727264Chloridazone 175 131414117Chloridazone 350 2728302922Chloridazone 700 5463645746Compound 36 + Chloridazone 4 + 700 57 54 67 63 83 74 78 69 63 57 Compound 36 + Chloridazone 8 + 350 56 31 54 31 95 68 96 67 88 59 Compound 36 + Chloridazone 16 +175 38 30 31 26 79 76 82 75 71 67
Table 27
Component g / ha Data (measured value / calculated value) [0122] 23] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0027282036 8 5554544836 16 2014727264Bentazona 125 009108Bentazona 250 00222218Bentazona 500 00495245Compound 36 + 4 + 6 0 7 0 66 63 68 65 64 56 Bentazona 500 Compound 36 + 8 + 22 5 21 5 88 64 90 64 91 57 Bentazona 250 Compound 36 + 16 + 23 20 17 14 84 74 82 75 74 67 Bentazona 125
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Table 28
Component g / ha Data (measured value / calculated value) [0124] 25] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0027282036 8 5554544836 16 2014727264Bromoxynil 50 001257Bromoxynil 100 00302021Bromoxynil 200 00604851Compound 36 + Bromoxynil 4 +200 4 0 9 0 81 71 71 63 67 61 Compound 36 + Bromoxynil 8 +100 21 5 22 5 93 68 95 63 85 59 Compound 36 + Bromoxynil 16 +50 25 20 22 14 81 75 79 73 76 67
Table 29
Component g / ha Data (measured value / calculated value) [0126] 27] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum 36 4 0027282036 8 5554544836 16 2014727264Propanil 375 117101010Propanil 750 2122232724Propanil 1500 4645565658Compound 36 + Propanil 4 + 1500 51 46 53 45 72 68 78 68 74 66 Compound 36 + Propanil 8 +750 48 25 47 25 85 65 90 66 92 60 Compound 36 + Propanil 16 +375 31 28 27 20 84 75 78 75 76 68
Comparative Examples [0128] The procedures related to tables 30 to 36 below were performed in the same way as those related to tables 4, 5, 10, 12, 15, 17 and 27, except for Butafenacil which was used instead of the compound of uracil. The two columns on the left for each gram in the tables below indicate the measured values of mortality, and the column on the right indicates the calculated values of mortality.
[0129] Table 30 below is for comparison with Table 4 and shows that an 8: 300 mixture of compound 36 and Glyphosate had the greatest effect.
Table 30
Component g / ha Data (measured value / calculated value) [0130]Echinochloa Digitaria san- Abutilon the- Aeschyno- Xanthium
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raw guineas ophrasti mene indicates spinosum Butafenacila 4 0022315Butafenacila 8 00354535Butafenacila 16 55516754Glyphosate 150 1288911Glyphosate 300 2318272230Glyphosate 600 4846594764Butafenacil + 4 + 52 48 52 46 68 60 75 59 69 69 Glyphosate 600 Butafenacil + Glyphosate 8 +300 26 23 19 18 52 52 66 57 64 55 Butafenacil + 16 + 16 16 21 13 59 55 76 70 67 59 Glyphosate 150
[0132] Table 31 below is for comparison with Table 5 and shows that an 8: 150 mixture of compound 36 and Glufosinate had the greatest effect.
Table 3
Component g / ha Data (measured value / calculated value) [0133] 34] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Butafenacila 4 0022315Butafenacila 8 00354535(Butafenacila 16 55516754Glufosinate 75 15117513Glufosinate 150 2927251825Glufosinate 300 6057494656Butafenacil + Glufosinate 4 +300 62 60 67 57 58 50 73 58 71 63 Butafenacil + Glufosinate 8 +150 30 29 28 27 58 51 65 55 55 51 Butafenacil + Glufosinate 16 +75 24 19 26 16 55 54 72 69 66 60
[0135] Table 32 below is for comparison with Table 10 and shows that a 20: 100 mixture and a 40:50 mixture of compound 36 and Metamiphope had high effects.
Table 32
Component g / ha Data (measured value / calculated value) [0136] 37] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Butafenacila 20 1212555142Butafenacila 40 3040949990Butafenacila 80 5370100100100Metamifope 25 1111000Metamifope 50 2623000Metamifope 100 5748000Butafenacil + Metamifope 20 +100 76 62 64 54 56 55 60 51 50 42 Butafenacil + Me- 40 + 53 47 63 53 100 94 100 99 91 90
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tamifope 50 Butafenacil + Metamifope 80 +25 63 58 81 73 100 100 100 100 100 100
[0138] Table 33 below is for comparison with Table 12 and shows that a 20: 100 mixture, a 40:50 mixture and an 80:25 mixture of compound 36 and Cletodim showed high effects.
Table 33
Component g / ha Data (measured value / calculated value) [0139] 40] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Butafenacila 20 1212555142Butafenacila 40 3040949990Butafenacila 80 5370100100100Cletodim 25 116000Cletodim 50 3119000Cletodim 100 6545000Butafenacil + Cletodim 20 +100 76 69 58 52 62 55 59 51 42 42 Butafenacil + Cletodim 40 +50 52 51 57 51 100 94 100 99 93 90 Butafenacil + Cletodim 80 +25 60 58 73 72 100 100 100 100 100 100
[0141] Table 34 below is for comparison with Table 15 and shows that an 8: 2.5 mixture of compound 36 and Trifloxysulfuron had the highest effect.
Table 34
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Butafenacila 4 00142820Butafenacila 8 00354957Butafenacila 16 1015467174Trifloxysulfuron 1.25 8812913Trifloxysulfuron 2.5 2426282530Trifloxysulfuron 5 5651615862Butafenacil + Trifloxysulfuron 4 + 5 59 56 52 51 76 67 76 70 70 70 Butafenacil + Trifloxysulfuron 8 +2.5 30 24 34 26 56 53 65 62 77 70 Butafenacil + Trifloxysulfuron 16 +1.25 22 17 30 22 58 52 82 74 78 77
[0144] Table 35 below is for comparison with Table 17 and shows that an 8: 200 mixture and a 16: 100 mixture of compound 36 and 2,4-D had the highest effect.
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Table 35
Component g / ha Data (measured value / calculated value) [0145] 46] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Butafenacila 4 0051015Butafenacila 8 05203035Butafenacila 16 5103545602,4-D 100 0077102,4-D 200 002124222,4-D 400 00475150Butafenacil +2,4-D 4 +400 0 0 0 0 59 50 72 56 61 58 Butafenacil +2,4-D 8 +200 5 0 5 5 48 36 66 46 68 49 Butafenacil +2,4-D 16 +100 10 5 15 10 55 40 61 49 74 64
[0147] Table 36 below is for comparison with Table 27 and shows that an 8: 250 mixture and a 16: 125 mixture of compound 36 and Bentazone had the highest effect.
Table 36
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Xanthium spinosum Butafenacila 4 00152010Butafenacila 8 00454025Butafenacila 16 105606555Bentazona 125 009108Bentazona 250 00222218Bentazona 500 00495245Butafenacila + Bentazona 4 + 500 4 0 4 0 70 57 71 62 55 51 Butafenacila + Bentazona 8 + 250 9 0 10 0 65 57 69 53 58 38 Butafenacila + Bentazona 16 +125 29 10 9 5 75 64 76 69 70 58
[0150] As described above, the mixture of the conventional non-selective herbicide and the uracil compound showed a greater herbicidal activity than that of each compound and also showed a greater herbicidal activity than the mixture comprising Butafenacil in place of the uracil compound.
Example 2: Herbicidal composition for dry field agriculture [0151] In the case of herbicidal compositions for dry field agriculture, weeds in the initial growth stage (5 cm or less) in the fields of
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Experimental Examples [0152] Tables 37 to 48 below show the plant mortality (herbicidal activities) obtained when Alopecurus aequalis, Porippa islandica, Capsella bursapastoris, Lamium amplexicaule and wheat or Echinochloa crus, Digitaria sanguinalis, Abutilon theophrasti, Aeschynomene indica and corn treated with the indicated amounts of uracil compounds, dry field farming herbicides, and dry field farming herbicides / uracil mixtures. When the measured values are higher than the calculated values, the test materials are designed to have significant herbicidal activities. The two columns on the left for each gram in the tables below indicate the measured values of mortality, and the column on the right indicates the calculated values of mortality.
Table 37
Component g / ha Data (measured value / calculated value) [0153] 54] Alopecurus aequalis Icelandic Porippa Capsella bursapastoris Lamium amplexicaule Wheat 36 1 010510036 2 0302530036 4 105545501Isoproturon 150 151011120Isoproturon 300 322629250Isoproturon 600 645363491Compound 36 + Isoproturon 1 +600 74 64 62 58 69 65 59 54 1 1 Compound 36 + Isoproturon 2 +300 56 32 76 48 75 46 77 47 0 0 Compound 36 + Isoproturon 4 +150 29 24 68 59 56 51 60 56 1 1
Table 3 ) 8 Component g / ha Data (measured value / calculated value) [0155] 56] Alopecurus aequalis Icelandic Porippa Capsella bursapastoris Lamium amplexicaule Wheat 36 1 010510036 2 0302530036 4 105545501Mesosulfuron 2 151210130Mesosulfuron 4 322730260Mesosulfuron 8 646159551
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Compound 36 + Mesosulfuron 1 + 8 68 64 70 65 67 61 70 60 1 1 Compound 36 + Mesosulfuron 2 + 4 55 32 80 49 78 47 78 48 0 0 Compound 36 + Mesosulfuron 4 + 2 32 24 64 61 60 50 64 56 1 1
Table 39
Component g / ha Data (measured value / calculated value) [0157] 58] Alopecurus aequalis Icelandic Porippa Capsella bursapastoris Lamium amplexicaule Wheat 36 1 010510036 2 0302530036 4 105545501Metsulfuron 1 057110Metsulfuron 2 02024290Metsulfuron 4 04548570Compound 36 +Metsulfuron 1 + 4 8 0 61 51 60 51 70 61 0 0 Compound 36 +Metsulfuron 2 + 2 15 0 73 44 70 43 79 50 0 0 Compound 36 +Metsulfuron 4 + 1 17 10 66 57 57 49 60 56 1 1
Table 40
Component g / ha Data (measured value / calculated value) [0159] 60] Alopecurus aequalis Icelandic Porippa Capsella bursapastoris Lamium amplexicaule Wheat 36 1 010510036 2 0302530036 4 105545501Diflufenican 37.5 056100Diflufenican 75 02021240Diflufenican 150 04045471Compound 36 + Diflufenican 1 +150 4 0 51 46 54 48 62 52 1 1 Compound 36 + Diflufenican 2 + 75 15 0 70 44 66 40 77 46 0 0 Compound 36 + Diflufenican 4 +37.5 16 10 65 57 55 48 62 55 1 1
Table 41
Component g / ha Data (measured value / calculated value) [0161] 62] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Nicosulfuron 5 1078110Nicosulfuron 10 242426300Nicosulfuron 20 505062650Compound 36 + Nicosulfuron 1 + 20 57 50 55 50 78 68 76 69 0 0
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Compound 36 + Nicosulfuron 2 + 10 58 24 55 24 88 52 85 47 0 0 Compound 36 + Nicosulfuron 4 + 5 20 15 20 16 61 54 54 51 1 1
Table 42
Component g / ha Data (measured value / calculated value) [0163] 64] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Iodosulfuron 1.25 71213120Iodosulfuron 2.5 242730240Iodosulfuron 5 585661471Compound 36 + Iodosulfuron 1 + 5 62 58 65 56 73 67 56 52 1 1 Compound 36 + Iodosulfuron 2 + 2.5 63 24 65 27 84 54 70 43 0 0 Compound 36 + 4 + 16 12 23 20 63 56 59 51 1 1 Iodosulfuron 1.25
Table 43
Component g / ha Data (measured value / calculated value) [0165] 66] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Florassulam 1 001280Florassulam 2 0023180Florassulam 4 0054460Compound 36 + Florassulam 1 + 4 3 0 3 0 69 61 60 51 0 0 Compound 36 + Florassulam 2 + 2 15 0 15 0 79 50 64 39 0 0 Compound 36 + Florassulam 4 + 1 9 5 14 10 63 56 56 49 1 1
Table 44
Component g / ha Data (measured value / calculated value) [0167] 68] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Mesotrione 15 0015110Mesotrione 30 5529270Mesotrione 60 151058541Compound 36 + Mesotrione 1 + 60 24 15 15 10 70 64 69 59 1 1 Compound 36 + Mesotrione 2 + 30 21 5 22 5 87 54 72 45 0 0 Compound 36 + 4 + 15 11 5 15 10 61 57 57 51 1 1
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Mesotrione
Table 45
Component g / ha Data (measured value / calculated value) Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Isoxaflutol 12.5 14101290Isoxaflutol 25 292431280Isoxaflutol 50 615362560Compound 36 + Isoxaflutol 1 + 50 67 61 60 53 75 68 69 60 0 0 Compound 36 + Isoxaflutol 2 + 25 65 29 58 24 89 55 85 46 0 0 Compound 36 + Isoxaflutol 4 +12.5 25 19 28 19 65 56 58 50 1 1
Table 46
Component g / ha Data (measured value / calculated value) [0171] 72] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Flufenacete 87.5 77960Flufenacete 175 242223180Flufenacete 350 505346461Compound 36 + Flufenacete 1 + 350 56 50 60 53 61 54 59 51 1 1 Compound 36 + Flufenacete 2 + 175 60 24 58 22 85 50 75 39 0 0 Compound 36 + 4 + 15 12 24 16 63 54 56 48 1 1 Flufenacete 87.5
Table 47
Component g / ha Data (measured value / calculated value) [0173] 74] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Sulfentrazone 75 001270Sulfentrazone 150 51025250Sulfentrazone 300 202856531Compound 36 + Sulfentrazone 1 + 300 23 20 31 28 66 63 66 58 1 1 Compound 36 + Sulfentrazone 2 + 150 22 5 28 10 80 51 78 43 0 0 Compound 36 + Sulfentrazone 4 + 75 9 5 16 10 60 56 58 49 1 1
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Table 48
Component g / ha Data (measured value / calculated value) [0175] 76] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn 36 1 001510036 2 003525036 4 51050451Carfentrazone 2.5 0030200Carfentrazone 5 0050450Carfentrazone 10 5575701Compound 36 + Carfentrazone 1 + 10 13 5 9 5 85 79 77 73 1 1 Compound 36 + Carfentrazone 2 + 5 15 0 15 0 90 68 92 59 0 0 Compound 36 + Carfentrazone 4 + 2.5 14 5 16 10 75 65 63 56 1 1
Comparative Examples [0177] The procedures related to Tables 49 and 50 below were performed in the same way as those related to Tables 38 and 44, except the Carfentra zone that was used instead of the uracil compound. The two columns on the left for each gram in the tables below indicate the measured values of mortality, and the column on the right indicates the calculated values of mortality.
[0178] Table 49 below is for comparison with Table 38 and shows that a 2: 4 mixture of compound 36 and Carfentrazone had the highest herbicidal effect.
Table 49
Component g / ha Data (measured value / calculated value) [0179] 30] Alopecurus aequalis Icelandic Porippa Capsella bursapastoris Lamium amplexicaule Wheat Carfentrazone 1 05050Carfentrazone 2 01515200Carfentrazone 4 04035400Mesosulfuron 2 151210130Mesosulfuron 4 322730260Mesosulfuron 8 646159551Carfentrazone + Mesosulfuron 1 + 8 68 64 63 63 65 59 68 57 1 1 Carfentrazone + Mesosulfuron 2 + 4 33 32 37 38 52 40 55 40 1 0 Carfentrazone + Mesosulfuron 4 + 2 23 15 15 47 50 41 60 48 0 0
[0181] Table 50 below is for comparison with Table 44 and shows that a
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Table 50
Component g / ha Data (measured value / calculated value) [0182] 83] Raw Echinochloa Digitaria sanguinalis Abutilon theophrasti Aeschynomene indica Corn Carfentrazone 1 001050Carfentrazone 2 0025200Carfentrazone 4 0045400Mesotrione 15 0015110Mesotrione 30 5529270Mesotrione 60 151058541Carfentrazone + Mesotrione 1 + 60 20 15 20 10 70 62 68 56 1 1 Carfentrazone + Mesotrione 2 + 30 14 5 7 5 60 47 55 42 0 0 Carfentrazone + Mesotrione 4 + 15 8 0 4 0 65 53 60 46 1 0
[0184] As can be seen in Tables 37 to 50 above, the mixture of the uracil compound and the conventional dry field farming herbicide showed a greater herbicidal activity than that of each compound and also showed a greater herbicidal activity than the mixture comprising Carfentrazone in place of the uracil compound. In addition, the mixture of the uracil compound and the conventional dry field herbicide did not show herbicidal activity for wheat and corn, suggesting that it can be used as a herbicidal composition for dry field agriculture.
Example 3: Herbicidal composition for rice farming [0185] In the case of herbicidal compositions, weeds in the rice fields were treated with compositions comprising the uracil composition and the herbicidally active compound above 25 days after rice transplantation.
Experimental Examples [0186] Tables 51 and 52 below show that the plant mortalities (herbicidal activities) obtained when Monochoria vaginalis, Ludwigia prostrate and a rice plant were treated with the indicated amounts of uracil compounds, herbicides for paddy farming and herbicide mixtures for agriculture
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48/58 rice / uracil compost, and Tables 53 to 77 below show the plant mortalities obtained when raw Monochoria vaginalis and Echinochloa were treated with the indicated amounts. When the measured values are higher than the calculated values, the test materials are designed to have significant herbicidal activities. The two columns on the left for each gram in the tables below indicate the measured values of mortality, and the column on the right indicates the calculated values of mortality.
Table 51
Component g / ha Data (measured value / calculated value) [0187] 188] Monochoria vaginalis Ludwigia prostrate Rice plant 36 2.5 515036 5 3035036 10 50551Bensulfurone 10 15200Bensulfurone 20 35400Bensulfurone 40 51551Compound 36 + Bensulfurone 2.5 + 40 56 53 66 62 1 1 Compound 36 + Bensulfurone 5 + 20 88 55 96 61 0 0 Compound 36 + Bensulfurone 10 + 10 62 58 68 64 1 1
Table 52
Component g / ha Data (measured value / calculated value) Monochoria vaginalis Ludwigia prostrate Rice plant 36 2.5 515036 5 3035036 10 50551Pyrazosulfuron 2.5 15200Pyrazosulfuron 5 40450Pyrazosulfuron 10 67621Compound 36 + Pyrazosulfuron 2.5 + 10 79 69 71 68 1 1 Compound 36 + Pyrazosulfuron 5 + 5 88 58 100 64 0 0 Compound 36 + Pyrazosulfuron 10 + 2.5 61 58 67 64 1 1
Table 53
Component g / ha Data (measured value / calculated value) [0191] 0192] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Azimsulfurone 5 50 - 30 -
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Compound 36 + Azimsulfurone 5 + 5 90 65 55 30
Table 54
Component g / ha Data (measured value / calculated value) Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Cinosulfurone 10 30 - 20 - Compound 36 + Cinosulfurone 5 + 10 80 51 45 20
Table 55
Component g / ha Data (measured value / calculated value) [0195] 0196] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Cyclosulfamurone 11 50 - 30 - Compound 36 + Cyclosulfamurone 5 + 11 90 65 45 30
Table 56
Component g / ha Data (measured value / calculated value) Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Halosulfuron 11 30 - 30 - Compound 36 + Halosulfuron 5 + 11 85 51 40 20
Table 57
Component g / ha Data (measured value / calculated value) [0199] 0200] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Imazosulfuron 18 40 - 20 - Compound 36 + Imazosulfuron 5 + 18 90 58 45 20
Table 58
Component g / ha Data (measured value / calculated value) [0201] ) 2021 Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Orthosulfamuron 17.5 40 - 10 - Compound 36 + Orthosulfamuron 5 + 17.5 85 58 35 10
Table 59
Component g / ha Data (measured value / calculated value) [0203] 0204] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Piriminobaque 11 0 - 50 - Compound 36 + Piriminobaque 5 + 11 55 30 85 50
Table 60 ______________________________________________
Component | g / ha | Data (measured value / calculated value)
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[0205] 0206] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Pirimissulfan 16.5 50 - 40 - Compound 36 + Pirimisulfan 5 + 16.5 95 65 65 40
Table 61
Component g / ha Data (measured value / calculated value) [0207] 0208] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Propirisulfuron 18 45 - 45 - Compound 36 + Propirisulfuron 5 + 18 90 61.5 70 45
Table 62
Component g / ha Data (measured value / calculated value) [0209] 0210] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Metazosulfuron 25 40 - 35 - Compound 36 + Metazosulfuron 5 + 25 90 58 65 35
Table 63
Component g / ha Data (measured value / calculated value) [0211] 0212] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Triafamona 12.5 10 - 50 - Compound 36 + Triafamone 5 + 12.5 70 37 80 50
Table 64
Component g / ha Data (measured value / calculated value) [0213] 0214] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Anilofos 75 0 - 50 - Compound 36 + Anilofos 5 + 75 55 30 85 50
Table 65
Component g / ha Data (measured value / calculated value) [0215] 0216] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Benzobicycle 50 30 - 0 - Compound 36 + Benzobicyclon 5 + 50 80 51 30 0
Table 66
Component g / ha Data (measured value / calculated value) [0217] 0218] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Bromobutide 225 50 - 0 - Compound 36 + Bromobutide 5 + 225 90 65 20 0
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Table 67
Component g / ha Data (measured value / calculated value) [0219] 0220] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Cafenstrol 50 30 - 20 - Compound 36 + Cafenstrol 5 + 50 85 51 45 20
Table 68
Component g / ha Data (measured value / calculated value) [0221] 0222] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Esprocarb 500 30 - 20 - Compound 36 + Esprocarb 5 + 500 85 51 55 20
Table 69
Component g / ha Data (measured value / calculated value) [0223] ) 224] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Etoxysulfuron 15 20 - 10 - Compound 36 + Etoxysulfuron 5 + 15 80 44 35 10
Table 70
Component g / ha Data (measured value / calculated value) [0225] 0226] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Fentrazamide 50 30 - 20 - Compound 36 + Fentrazamide 5 + 50 85 51 45 20
Table 71
Component g / ha Data (measured value / calculated value) [0227] 0228] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Indanofan 37.5 0 - 25 - Compound 36 + Indanofan 5 + 37.5 65 30 50 25
Table 72
Component g / ha Data (measured value / calculated value) [0229] 0230] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Mefenacete 200 30 - 30 - Compound 36 + Mefenacete 5 + 200 80 51 55 30
Table 73
Component g / ha Data (measured value / calculated value) [0231] 0232] Monochoria vaginalis Raw Echinochloa 36 5 30 | - 0 1-
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molinate 500 0 - 50 - Compound 36 + molinate 5 + 500 50 30 80 50
Table 74
Component g / ha Data (measured value / calculated value) [0233] 0234] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Oxaziclomefona 12.5 0 - 30 - Compound 36 + Oxaziclomefone 5 + 12.5 55 30 65 30
Table 75
Component g / ha Data (measured value / calculated value) [0235] 0236] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Pyributicarb 150 20 - 20 - Compound 36 + Pyributicarb 5 + 150 75 44 45 20
Table 76
Component g / ha Data (measured value / calculated value) [0237] 0238] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Piriftalid 37.5 0 - 30 - Compound 36 + Piriftalid 5 + 37.5 65 30 50 30
Table 77
Component g / ha Data (measured value / calculated value) [0239] 0240] Monochoria vaginalis Raw Echinochloa 36 5 30 - 0 - Quinoclamine 450 0 - 0 - Compound 36 + Quinoclamine 5 + 450 65 30 25 0
Comparative Example [0241] The procedure related to Table 78 below was performed in the same way as the procedure related to Table 52, except for Carfentrazone which was used instead of the uracil compound.
[0242] Table 78 below is for comparison with Table 52 and shows that a 2.5: 10 mixture and a 5: 5 mixture of compound 36 and Pyrazosulfuron had the highest herbicidal effect. The two columns on the left for each gram in the table below indicate the measured values of mortality, and the column on the right indicates the calculated values of mortality.
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Table 78
Component g / ha Data (measured value / calculated value) [0243] 244] Monochoria vaginalis Ludwigia prostrate Rice plant Carfentrazone 2.5 0100Carfentrazone 5 20350Carfentrazone 10 45500Pyrazosulfuron 2 20150Pyrazosulfuron 4 40350Pyrazosulfuron 8 63651Carfentrazone + Pyrazosulfuron 2.5 + 8 70 63 72 69 1 1 Carfentrazone + Pyrazosulfuron 5 + 4 60 52 60 58 1 0 Carfentrazone + Pyrazosulfuron 10 + 2 65 56 65 58 0 0
[0245] As can be seen in Tables 51 to 78 above, the mixture of the uracil compound and the conventional rice paddy farming herbicide showed greater herbicidal activity than that of each compound and also showed greater herbicidal activity than the mixture comprising Carfentrazone in place of the uracil compound. In addition, the mixture of the uracil compound and the conventional rice farming herbicide did not show herbicidal activity for the rice plant, suggesting that it can be used as a herbicidal composition for rice farming.
Example 4. Non-selective herbicidal composition comprising 1 uracil compound and 2 herbicidally active compounds [0246] Weeds in the growing phase (30-40 cm) in fallow areas and orchards were treated with non-selective herbicidal compositions containing 1 compound of uracil and 2 herbicidally active compounds.
Experimental Example [0247] Table 79 below shows the plant mortalities (herbicidal activities) obtained when lolium and wild amaranth were treated with the indicated amounts of non-selective herbicides, and mixtures of 2 herbicides / 1 uracil compound. When the measured values are higher than the calculated values, mate
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54/58 test plants have significant herbicidal activities. The two columns on the left for each gram in the tables below indicate the measured values of mortality, and the column on the right indicates the calculated values of mortality.
Table 79
Component g ai / ha Data (measured value / calculated value) [0248] 0249] lolium Wild Amaranth 36 8 30 - 40 - Glyphosate-IPA 300 10 - 10 - Compound 36 + Glyphosate-IPA 8 +300 65 37 80 46 Clopyralide 125 0 - 10 - Compound 36 + Glyphosate-IPA + Clopyralide 8 +300 +125 95 65 100 82 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Sulcotrione 75 20 - 20 - Compound 36 + Glyphosate-IPA + Sulcotrione 8 + 300 + 75 98 72 100 84 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Clomazone 175 15 - 30 - Compound 36 + Glyphosate-IPA + Clomazone 8 + 300 + 175 99 70 100 86 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Picolinafena 25 0 - 25 - Compound 36 + Glyphosate-IPA + Picolinafen 8 + 300 + 25 85 65 100 85 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Imazamox 8.3 30 - 20 - Compound 36 + Glyphosate-IPA + Imazamox 8 + 300 + 8.3 100 76 99 84 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Diclofope 175 30 - 0 - Compound 36 + Glyphosate-IPA + Diclofope 8 + 300 + 175 99 76 90 80 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Diflufenzopyr 12.5 20 - 20 - Compound 36 + Glyphosate-IPA + Diflufenzopyr 8 + 300 +12.5 93 72 99 84 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Isoxabena 31 0 - 30 - Compound 36 + Glyphosate-IPA + Isoxaben 8 + 300 + 31 85 65 100 86 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Asulam 1250 25 - 20 -
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Compound 36 + Glyphosate-IPA + Asulam 8 + 300 +1250 98 74 99 84 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Bilanafos 500 30 - 15 - Compound 36 + Glyphosate-IPA + Bilanafos 8 + 300 + 500 100 76 99 83 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Etofumesate 250 25 - 20 - Compound 36 + Glyphosate-IPA + Etofumesate 8 + 300 + 250 99 74 95 84 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Atrazine 200 30 - 25 - Compound 36 + Glyphosate-IPA + Atrazine 8 + 300 + 200 100 76 100 85 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Oxadiazone 500 30 - 30 - Compound 36 + Glyphosate-IPA + Oxadiazone 8 + 300 + 500 100 76 100 86 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Acetochlor 375 30 - 10 - Compound 36 + Glyphosate-IPA + Acetochlor 8 + 300 + 375 100 76 95 82 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Pendimethalin 250 30 - 20 - Compound 36 + Glyphosate-IPA + Pendimethalin 8 + 300 + +250 100 76 98 84 Compound 36 + Glyphosate-IPA 8 + 300 65 37 80 46 Aminopyralide 250 0 - 20 - Compound 36 + Glyphosate-IPA + Aminopyralide 8 + 300 + 250 80 65 100 84 36 8 30 - 40 - Glufosinate-ammonium 150 10 - 20 - Compound 36 + Glufosinate-ammonium 8 + 150 60 37 85 52 Clopyralide 125 0 - 10 - Compound 36 + Glufosinate-ammonium + Clopyralide 8 + 150 + 125 90 60 100 87 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Sulcotrione 75 20 - 20 - Compound 36 + Glufosinate-ammonium + Sulcotrione 8 + 300 + 75 95 72 98 84 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Clomazone 175 15 - 30 - Compound 36 + Glufosinate-ammonium + Clomazo- 8 + 300 + 175 95 70 99 86
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atCompound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Picolinafena 25 0 - 25 - Compound 36 + Glufosinate-ammonium + Picolinafen 8 + 300 + 25 85 65 99 85 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Imazamox 8.3 30 - 20 - Compound 36 + Glufosinate-ammonium + Imazamox 8 + 300 + 8.3 95 76 98 84 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Diclofope 175 30 - 0 - Compound 36 + Glufosinate-ammonium + Diclofope 8 + 300 + 175 99 76 90 80 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Diflufenzopyr 12.5 20 - 20 - Compound 36 + Glufosinate-ammonium + Diflufenzopyr 8 + 300 +12.5 95 72 95 84 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Isoxabena 31 0 - 30 - Compound 36 + Glufosinate-ammonium + Isoxaben 8 + 300 + 31 80 65 100 86 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Asulam 1250 25 - 20 - Compound 36 + Glufosinate-ammonium + Asulam 8 + 300 + 1250 95 74 98 84 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Bilanafos 500 30 - 15 - Compound 36 + Glufosinate-ammonium + Bilanafos 8 + 300 + 500 98 76 95 83 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Etofumesate 250 25 - 20 - Compound 36 + Glufosinate-ammonium + Etofumesate 8 + 300 + 250 98 74 93 84 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Atrazine 200 30 - 25 - Compound 36 + Glufosinate-ammonium + Atrazine 8 + 300 + 200 98 76 99 85 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Oxadiazone 500 30 - 30 - Compound 36 + Glufosinate-ammonium + Oxadiazone 8 + 300 + 500 99 76 100 86
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Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Acetochlor 375 30 - 10 - Compound 36 + Glufosinate-ammonium + Acetochlor 8 + 300 + 375 100 76 93 82 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Pendimethalin 250 30 - 20 - Compound 36 + Glufosinate-ammonium + Pendimethalin 8 + 300 + 250 96 76 100 84 Compound 36 + Glufosinate-ammonium 8 + 300 65 37 80 46 Aminopyralide 250 0 - 20 - Compound 36 + Glufosinate-ammonium + Aminopyralide 8 + 300 + 250 80 65 98 84
[0250] As described above, the mixture of the two conventional non-selective herbicides and the uracil compound showed greater herbicidal activity.
[0251] As described above, the herbicidal composition according to the present invention comprises as active ingredients, the uracil compound represented by formula 1 and a herbicidally active compound and, therefore, has excellent herbicidal activity despite having a very high compatibility with cultures. In addition, the herbicidal composition of the present invention shows excellent effects not only in the selective control of monocotyledonous and dicotyledonous weeds in various crops, for example, wheat, barley, oats and corn, but also in the control of monocotyledonous and dicotyledonous weeds in the areas semi and non-selective.
[0252] As can be seen from the results of the examples above carried out by the present inventors, the inventive herbicidal composition comprising both the uracil compound and the herbicidally active compound showed excellent herbicidal activity thanks to the synergistic action of these active ingredients compared to the herbicidal composition comprising the uracil compound and the herbicidally active compound individually. This increase in herbicidal activity is a notable effect, which could not be predicted by those skilled in the art.
[0253] Furthermore, the herbicidal composition of the present invention could be soft
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[0254] In this sense, the herbicidal composition of the present invention has excellent herbicidal activity against weeds, can selectively control monocot and dicot weeds in useful crops and can also control monocot and dicot weeds in semi-selective and non-selective areas .
权利要求:
Claims (9)
[1]
1. Herbicidal composition CHARACTERIZED by the fact that it comprises, as active ingredients, a herbicidally active compound and an uracil compound represented by the following formula 1 or an agrochemically acceptable salt thereof:

Formula 1 where:
R 1 and R5 represent a methyl group;
R2, R 3 and R4 represent a hydrogen atom;
X represents O or S;
Y represents a methylene group;
W represents O; and
Z represents a chlorine atom, where X represents O and the herbicidally active compound is glyphosate or glufosinate, where X represents S and the herbicidally active compound is selected from the group consisting of glyphosate, glufosinate, phenoxaprope, clodinafope, fluazifope, haloxifope , metamiphope, pinoxaden, cletodim, tralcoxidim, imazetapyr, trifloxysulfuron, bispiribach-sodium, 2,4-D, dicamba, picloram, fluroxypir, triclopyr, MCPA, mecoprop, quincloraque, MCPB, chloridazone, bentazone, bentazone, bentazone, bentazone, bentazone, bentazone , metsulfuron, diflufenicano, nicosulfuron, iodosulfuron, florassulam, mesotrione, isoxaflutol, flufenacet, sulfentrazone, carfentrazone, bensulfuron and
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[2]
2/3 pyrazosulfuron.
2. Herbicidal composition, according to claim 1, CHARACTERIZED by the fact that the composition comprises:
i) two herbicidally active compounds, where one of the herbicidally active compounds is glyphosate-isopropylammonium, and the other herbicidally active compound is selected from the group consisting of clopyralide, sulcotrione, clomazone, picolinafen, imazamox, diclofope-methyl, diflufenzopyr, isoxaben, asulam, bilanafos, etofumesate, atrazine, oxadiazone, acetochlor, pendimethalin and aminopyralide; and ii) the uracil compound represented by formula 1 or an agrochemically acceptable salt thereof, where X represents S.
[3]
3. Herbicidal composition, according to claim 2, CHARACTERIZED by the fact that the composition comprises:
i) two herbicidally active compounds, where one of the herbicidally active compounds is glufosinate-ammonium, and the other herbicidally active compound is selected from the group consisting of clopyralide, sulcotrione, clomazone, picolinafen, imazamox, diclofop-methyl, diflufenzopyr, isoxaben, asulam, bilanafos, etofumesate, atrazine, oxadiazone, acetochlor, pendimethalin and aminopyralide; and ii) the uracil compound represented by formula 1 or an agrochemically acceptable salt thereof, where X represents S.
[4]
4. Herbicidal composition according to claim 1, CHARACTERIZED by the fact that the composition further comprises a solid or liquid diluent and a surfactant.
[5]
5. Herbicidal composition according to claim 4, CHARACTERIZED by the fact that the diluent or surfactant is contained in an amount of 0.1 to 99.9% by weight based on the total weight of the composition.
[6]
6. Herbicidal composition according to claim 1,
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CHARACTERIZED by the fact that the herbicidal composition is in the form of wettable powder, suspensions, emulsifiable concentrates, emulsions, microemulsions, soluble concentrates, dispersible concentrates, water-dispersible granules, granules, powders, suspension concentrates, granules floating in water or tablets.
[7]
7. Herbicidal composition according to claim 1, CHARACTERIZED by the fact that the active ingredients further comprise an ingredient selected from the group consisting of acetyl-CoA carboxylase (ACC) inhibitors, acetolactate synthase (ALS) inhibitors, amides, auxin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, enolpyruvylshiquimite 3-phosphate synthase (ESPS) inhibitors, glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protoporphyrogen IX inhibidase inhibitors, photosynthesis inhibitors , synergistic agents, growth substances, cell wall biosynthesis inhibitors and known herbicides.
[8]
8. Herbicidal composition according to any one of claims 1 to 7, CHARACTERIZED by the fact that the herbicidal composition is used in dry field or rice field agriculture.
[9]
9. Herbicidal composition according to any one of claims 1 to 7, CHARACTERIZED by the fact that the herbicidal composition is used as a non-selective herbicide.
类似技术:
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US10206399B2|2019-02-19|Herbicidal composition comprising uracil compound as active ingredient
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US20040171488A1|2004-09-02|N-aryl-uracils based Herbicides
CZ20021728A3|2002-10-16|Synergistic herbicidal composition of active substances and their use
PT2272353E|2012-11-08|Herbicides based on substituted thien-3-yl-sulfonylamino|carbonyl-triazolin|ones and dicamba
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KR20020035601A|2002-05-11|Selective herbicides on the basis of N-aryl-triazoline|ones
同族专利:
公开号 | 公开日
EA201401085A1|2015-01-30|
EP2836072A4|2015-11-11|
CA2867693A1|2013-10-17|
CL2014002700A1|2015-05-15|
AR090661A1|2014-11-26|
JP2015514723A|2015-05-21|
IL235087A|2017-07-31|
EP2836072B1|2018-11-21|
EA026666B1|2017-05-31|
HUE043469T2|2019-08-28|
ZA201406866B|2016-05-25|
CN104320972A|2015-01-28|
PL2836072T3|2019-05-31|
TR201902463T4|2019-03-21|
WO2013154396A1|2013-10-17|
CN104320972B|2017-05-24|
ES2711895T3|2019-05-08|
JP2017014230A|2017-01-19|
NZ700034A|2016-01-29|
AU2013247523B2|2015-12-03|
CO7170153A2|2015-01-28|
PH12014502278B1|2014-12-10|
AU2016201412A1|2016-03-24|
JP5980412B2|2016-08-31|
KR20140138913A|2014-12-04|
US20150024940A1|2015-01-22|
CR20140472A|2015-02-03|
PH12014502278A1|2014-12-10|
MX2014012072A|2015-03-06|
AU2013247523A1|2014-10-09|
MY174754A|2020-05-13|
MX351737B|2017-10-26|
KR101686860B1|2016-12-22|
CA2867693C|2017-09-05|
EP2836072A1|2015-02-18|
US10206399B2|2019-02-19|
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法律状态:
2018-03-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
2019-05-21| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|
2019-09-17| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
2019-10-08| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 12/04/2013, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 12/04/2013, OBSERVADAS AS CONDICOES LEGAIS |
优先权:
申请号 | 申请日 | 专利标题
KR10-2012-0038002|2012-04-12|
KR20120038002|2012-04-12|
PCT/KR2013/003107|WO2013154396A1|2012-04-12|2013-04-12|Herbicidal composition comprising uracil compound as active ingredient|
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